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Modifying Chemical Landscapes by Coupling to Vacuum Fields
Abstract
Electromagnetic vacuum fields are omnipresent in our universe, inducing many events such as spontaneous emission, Lamb shift, and Van der Waals forces. As demonstrated here, a chemical reaction can be influenced by strongly coupling the energy landscape governing the reaction pathway to vacuum fields in an optical cavity (see picture; MC=merocyanine).
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Citations
Cited by
Strong coupling between surface plasmon polaritons and emitters: a review
Törmä, P., & Barnes, W. L. (2015) · Reports on Progress in Physics · doi:10.1088/0034-4885/78/1/013901 · Cited by 1,644
Tame, M. S., McEnery, K. R., Özdemir, Ş. K., Lee, J., Maier, S. A., & Kim, M. S. (2013) · Nature Physics · doi:10.1038/nphys2615 · Cited by 1,573
Tilting a ground-state reactivity landscape by vibrational strong coupling
Thomas, A., Lethuillier-Karl, L., Nagarajan, K., Vergauwe, R. M. A., George, J., Chervy, T., Shalabney, A., Devaux, E., Genet, C., Moran, J., et al. (2019) · Science · doi:10.1126/science.aau7742 · Cited by 852
Self-citationFlick, J., Ruggenthaler, M., Appel, H., & Rubio, A. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1615509114 · Cited by 573
Nonlinear optical signals and spectroscopy with quantum light
Dorfman, K. E., Schlawin, F., & Mukamel, S. (2016) · Reviews of Modern Physics · doi:10.1103/revmodphys.88.045008 · Cited by 361
Metadata
- Authors
- Hutchison, J. A., Schwartz, T., Genet, C., Devaux, E., & Ebbesen, T. W.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2012-01-10
- Volume
- 51
- Issue
- 7
- Pages
- 1592-1596
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2141742048
- Cited by
- 932
- References
- 0
- FWCI
- 7.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hutchison, J. A., Schwartz, T., Genet, C., Devaux, E., & Ebbesen, T. W. (2012). Modifying Chemical Landscapes by Coupling to Vacuum Fields. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201107033
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
