The DOI matches its Crossref record; 33 of the 33 references it cites were found in a registry or an index.
Tilting a ground-state reactivity landscape by vibrational strong coupling
Open accessAbstract
Shaking up reaction-site selectivity: It seems intuitive that putting vibrational energy into a chemical bond ought to promote selective cleavage of that bond. In fact, the relation of vibrational excitation to reactivity has generally proven subtler and more complex. Thomas et al. studied how strong coupling of specific vibrational modes to an optical cavity might influence a molecule with two competing reactive sites. The molecule had two silicon centers that could react with fluoride by respective cleavage of a Si–C or Si–O bond. Exciting the vibrations at either center slowed down the overall reaction while favoring otherwise disfavored Si–O cleavage. Science , this issue p. 615
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Cites
Optical properties of metallic films for vertical-cavity optoelectronic devices
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Hybrid Light–Matter States in a Molecular and Material Science Perspective
Ebbesen, T. W. (2016) · Accounts of Chemical Research · doi:10.1021/acs.accounts.6b00295 · Cited by 942
Self-citationModifying Chemical Landscapes by Coupling to Vacuum Fields
Hutchison, J. A., Schwartz, T., Genet, C., Devaux, E., & Ebbesen, T. W. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201107033 · Cited by 932
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Vibrationally Coherent Photochemistry in the Femtosecond Primary Event of Vision
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Conductivity in organic semiconductors hybridized with the vacuum field
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Self-citationCavity-Controlled Chemistry in Molecular Ensembles
Herrera, F., & Spano, F. C. (2016) · Physical Review Letters · doi:10.1103/physrevlett.116.238301 · Cited by 581
Laser Control of Chemical Reactions
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Ground‐State Chemical Reactivity under Vibrational Coupling to the Vacuum Electromagnetic Field
Thomas, A., George, J., Shalabney, A., Dryzhakov, M., Varma, S. J., Moran, J., Chervy, T., Zhong, X., Devaux, E., Genet, C., et al. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201605504 · Cited by 548
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Theoretical Advances in Polariton Chemistry and Molecular Cavity Quantum Electrodynamics
Mandal, A., Taylor, M. A. D., Weight, B. M., Koessler, E. R., Li, X., & Huo, P. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00855 · Cited by 270
Metadata
- Authors
- Thomas, A., Lethuillier-Karl, L., Nagarajan, K., Vergauwe, R. M. A., George, J., Chervy, T., Shalabney, A., Devaux, E., Genet, C., Moran, J., & Ebbesen, T. W.
- Venue
- Science
- Published
- 2019-02-08
- Volume
- 363
- Issue
- 6427
- Pages
- 615-619
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2912574264
- Cited by
- 852
- References
- 33
- FWCI
- 43.11
- Type
- journal article
- Language
- en
- Open access
- green
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- Thomas, A., Lethuillier-Karl, L., Nagarajan, K., Vergauwe, R. M. A., George, J., Chervy, T., Shalabney, A., Devaux, E., Genet, C., Moran, J., & Ebbesen, T. W. (2019). Tilting a ground-state reactivity landscape by vibrational strong coupling. Science. https://doi.org/10.1126/science.aau7742
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
