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Thermal Hydrogen‐Atom Transfer from Methane: The Role of Radicals and Spin States in Oxo‐Cluster Chemistry
Abstract
Hydrogen‐atom transfer (HAT), as one of the fundamental reactions in chemistry, is investigated with state‐of‐the‐art gas‐phase experiments in conjunction with computational studies. The focus of this Minireview concerns the role that the intrinsic properties of gaseous oxo‐clusters play to permit HAT reactivity from saturated hydrocarbons at ambient conditions. In addition, mechanistic implications are discussed which pertain to heterogeneous catalysis. From these combined experimental/computational studies, the crucial role of unpaired spin density at the abstracting atom becomes clear, in distinct contrast to recent conclusions derived from solution‐phase experiments.
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Citations
Cites
Proton-coupled electron transfer
Huynh, M. H. V., & Meyer, T. J. (2007) · Chemical Reviews · doi:10.1021/cr0500030 · Cited by 1,659
Cited by
Grundner, S., Markovits, M. A. C., Li, G., Tromp, M., Pidko, E. A., Hensen, E. J. M., Jentys, A., Sanchez-Sanchez, M., & Lercher, J. A. (2015) · Nature Communications · doi:10.1038/ncomms8546 · Cited by 773
Solar-Energy-Mediated Methane Conversion
Song, H., Meng, X., Wang, Z.-J., Liu, H., & Ye, J. (2019) · Joule · doi:10.1016/j.joule.2019.06.023 · Cited by 478
Gür, T. M. (2016) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2015.10.004 · Cited by 340
Metadata
- Authors
- Dietl, N., Schlangen, M., & Schwarz, H.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2012-03-16
- Volume
- 51
- Issue
- 23
- Pages
- 5544-5555
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2064517416
- Cited by
- 421
- References
- 1
- FWCI
- 20.80
- Type
- journal article
- Language
- en
- Open access
- closed
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- Dietl, N., Schlangen, M., & Schwarz, H. (2012). Thermal Hydrogen‐Atom Transfer from Methane: The Role of Radicals and Spin States in Oxo‐Cluster Chemistry. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201108363
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