The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Single-site trinuclear copper oxygen clusters in mordenite for selective conversion of methane to methanol
Open accessAbstract
Copper-exchanged zeolites with mordenite structure mimic the nuclearity and reactivity of active sites in particulate methane monooxygenase, which are enzymes able to selectively oxidize methane to methanol. Here we show that the mordenite micropores provide a perfect confined environment for the highly selective stabilization of trinuclear copper-oxo clusters that exhibit a high reactivity towards activation of carbon–hydrogen bonds in methane and its subsequent transformation to methanol. The similarity with the enzymatic systems is also implied from the similarity of the reversible rearrangements of the trinuclear clusters occurring during the selective transformations of methane along the reaction path towards methanol, in both the enzyme system and copper-exchanged mordenite.
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Applications of Zeolites in Sustainable Chemistry
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Metadata
- Authors
- Grundner, S., Markovits, M. A. C., Li, G., Tromp, M., Pidko, E. A., Hensen, E. J. M., Jentys, A., Sanchez-Sanchez, M., & Lercher, J. A.
- Venue
- Nature Communications
- Published
- 2015-06-25
- Volume
- 6
- Issue
- 1
- Pages
- 7546-7546
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2162783646
- Cited by
- 773
- References
- 32
- FWCI
- 26.30
- Type
- journal article
- Language
- en
- Open access
- gold
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- Grundner, S., Markovits, M. A. C., Li, G., Tromp, M., Pidko, E. A., Hensen, E. J. M., Jentys, A., Sanchez-Sanchez, M., & Lercher, J. A. (2015). Single-site trinuclear copper oxygen clusters in mordenite for selective conversion of methane to methanol. Nature Communications. https://doi.org/10.1038/ncomms8546
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
