The DOI matches its Crossref record.
Three‐component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts
Abstract
Here comes the sun: A facile vicinal difunctionalization of alkenes, oxytrifluoromethylation, was established by visible-light-driven photoredox catalysis. Judicious choice of the CF3 source is key. Nucleophiles such as water, alcohols, and carboxylic acids can be used in this highly efficient (2–4 h) and regioselective (100 %) transformation using light-emitting diode (LED) lamps and natural sunlight. SET=single-electron transfer.
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Cited by
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Recent advances in photoinduced trifluoromethylation and difluoroalkylation
Pan, X., Xia, H., & Wu, J. (2016) · Organic Chemistry Frontiers · doi:10.1039/c6qo00153j · Cited by 283
Skin protection against UV light by dietary antioxidants
Fernández-García, E. (2014) · Food & Function · doi:10.1039/c4fo00280f · Cited by 108
Metadata
- Authors
- Yasu, Y., Koike, T., & Akita, M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2012-08-31
- Volume
- 51
- Issue
- 38
- Pages
- 9567-9571
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2105276976
- Cited by
- 551
- References
- 0
- FWCI
- 32.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Three‐component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts. https://app.cochat.ai/papers/10.1002/anie.201205071
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- Yasu, Y., Koike, T., & Akita, M. (2012). Three‐component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201205071
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