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Asymmetric Counteranion‐Directed Catalysis: Concept, Definition, and Applications
Abstract
Recently, the use of enantiomerically pure counteranions for the induction of asymmetry in reactions proceeding through cationic intermediates has emerged as an exciting new concept, which has been termed asymmetric counteranion‐directed catalysis (ACDC). Despite its success, the concept has not been fully defined and systematically discussed to date. This Review closes this gap by providing a clear definition of ACDC and by examining both clear cases as well as more ambiguous examples to illustrate the differences and overlaps with other catalysis concepts.
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Marcus, Y., & Hefter, G. (2006) · Chemical Reviews · doi:10.1021/cr040087x · Cited by 1,134
Cited by
Parmar, D., Sugiono, E., Raja, S., & Rueping, M. (2014) · Chemical Reviews · doi:10.1021/cr5001496 · Cited by 2,118
Applications of Supramolecular Anion Recognition
Busschaert, N., Caltagirone, C., Van Rossom, W., & Gale, P. A. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00099 · Cited by 1,249
Zhu, Y., Han, J., Wang, J., Shibata, N., Sodeoka, M., Soloshonok, V. A., Coelho, J. A. S., & Toste, F. D. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00778 · Cited by 640
Silver-catalysed reactions of alkynes: recent advances
Fang, G., & Bi, X. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00027k · Cited by 572
Chiral Photocatalyst Structures in Asymmetric Photochemical Synthesis
Genzink, M. J., Kidd, J. B., Swords, W. B., & Yoon, T. P. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00467 · Cited by 420
Metadata
- Authors
- Mahlau, M., & List, B.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2012-11-28
- Volume
- 52
- Issue
- 2
- Pages
- 518-533
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W1998740595
- Cited by
- 885
- References
- 1
- FWCI
- 34.70
- Type
- journal article
- Language
- en
- Open access
- closed
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