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Selective Catalytic Transfer Dehydrogenation of Alkanes and Heterocycles by an Iridium Pincer Complex
Abstract
Catalytic alkane dehydrogenation is a reaction with tremendous potential for application. We describe a highly active PSCOP‐pincer iridium catalyst for transfer dehydrogenation of cyclic and linear alkanes. The dehydrogenation of linear alkanes occurs under relatively mild conditions with high regioselectivity for α‐olefin formation. In addition, the catalyst system is very effective in the dehydrogenation of heterocycles to form heteroarenes and olefinic products.
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Citations
Cited by
Kumar, A., Daw, P., & Milstein, D. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00412 · Cited by 648
Jia, X., Qin, C., Friedberger, T., Guan, Z., & Huang, Z. (2016) · Science Advances · doi:10.1126/sciadv.1501591 · Cited by 534
“Compared to the (PCP)Ir complex (1), Brookhart’s bis(phosphinite)-ligated (POCOP)Ir complex (27) exhibits higher regioselectivity for formation of internal alkenes in catalytic n-alkane dehydrogenation (28).”
BackgroundSelf-citationWerkmeister, S., Neumann, J., Junge, K., & Beller, M. (2015) · Chemistry – A European Journal · doi:10.1002/chem.201500937 · Cited by 379
Dehydrogenation of Alkanes and Aliphatic Groups by Pincer-Ligated Metal Complexes
Kumar, A., Bhatti, T. M., & Goldman, A. S. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00247 · Cited by 346
Parasram, M., Chuentragool, P., Sarkar, D., & Gevorgyan, V. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b01628 · Cited by 284
Metadata
- Authors
- Yao, W., Zhang, Y., Jia, X., & Huang, Z.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-01-02
- Volume
- 53
- Issue
- 5
- Pages
- 1390-1394
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2111894677
- Cited by
- 179
- References
- 0
- FWCI
- 9.25
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yao, W., Zhang, Y., Jia, X., & Huang, Z. (2014). Selective Catalytic Transfer Dehydrogenation of Alkanes and Heterocycles by an Iridium Pincer Complex. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201306559
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
