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Active Mixed‐Valent MnOx Water Oxidation Catalysts through Partial Oxidation (Corrosion) of Nanostructured MnO Particles
Abstract
Yes, we CAN: Partial oxidation of inactive MnO nanoparticles by CeIV as oxidant gives active MnOx catalysts that are suitable for effective photochemical and electrochemical water oxidation. The active MnOx catalyst contains mixed-valent MnII, MnIII, and MnIV species (see picture; green and violet) interconnected through oxido bridges (red) with defects and disorders. MnOx is analogous to calcium–manganese oxide systems where the calcium sites are replaced by MnII or MnIII ions.
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Citations
Cites
Manganese oxide minerals: Crystal structures and economic and environmental significance
Post, J. E. (1999) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.96.7.3447 · Cited by 1,854
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Self-citation
Cited by
Transition‐Metal (Co, Ni, and Fe)‐Based Electrocatalysts for the Water Oxidation Reaction
Han, L., Dong, S., & Wang, E. (2016) · Advanced Materials · doi:10.1002/adma.201602270 · Cited by 1,769
Ultrathin Cobalt–Manganese Layered Double Hydroxide Is an Efficient Oxygen Evolution Catalyst
Song, F., & Hu, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5096733 · Cited by 1,163
Recent development in electrocatalysts for hydrogen production through water electrolysis
Anwar, S., Khan, F., Zhang, Y., & Djire, A. (2021) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2021.06.191 · Cited by 652
Recent Progresses in Electrocatalysts for Water Electrolysis
Khan, M. A., Zhao, H., Zou, W., Chen, Z., Cao, W., Fang, J., Xu, J., Zhang, L., & Zhang, J. (2018) · Electrochemical Energy Reviews · doi:10.1007/s41918-018-0014-z · Cited by 527
Advantageous crystalline–amorphous phase boundary for enhanced electrochemical water oxidation
Han, H., Choi, H., Mhin, S., Hong, Y.-R., Kim, K. M., Kwon, J., Ali, G., Chung, K. Y., Je, M., Umh, H. N., et al. (2019) · Energy & Environmental Science · doi:10.1039/c9ee00950g · Cited by 482
Metadata
- Authors
- Indra, A., Menezes, P. W., Zaharieva, I., Baktash, E., Pfrommer, J., Schwarze, M., Dau, H., & Driess, M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2013-10-31
- Volume
- 52
- Issue
- 50
- Pages
- 13206-13210
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2128723739
- Cited by
- 291
- References
- 2
- FWCI
- 13.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Active Mixed‐Valent MnOx Water Oxidation Catalysts through Partial Oxidation (Corrosion) of Nanostructured MnO Particles. https://app.cochat.ai/papers/10.1002/anie.201307543
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- Indra, A., Menezes, P. W., Zaharieva, I., Baktash, E., Pfrommer, J., Schwarze, M., Dau, H., & Driess, M. (2013). Active Mixed‐Valent MnOx Water Oxidation Catalysts through Partial Oxidation (Corrosion) of Nanostructured MnO Particles. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201307543
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