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A Cationic Metal–Organic Framework Consisting of Nanoscale Cages: Capture, Separation, and Luminescent Probing of Cr2O72− through a Single‐Crystal to Single‐Crystal Process
Abstract
Dichromate capture: A 3D cationic metal-organic framework consisting of distorted octahedral and tetrahedral cages was constructed by using Ag(I) and 4,4'-bis(1,2,4-triazole). The complex exhibits fast exchange, high trapping capacity, and good selectivity for Cr2 O7 (2-) through single-crystal to single-crystal transformation. The complex also features a bluish violet luminescence that is distinctly quenched after Cr2 O7 (2-) exchange.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Removal of chromium(VI) from aqueous solution by activated carbons: Kinetic and equilibrium studies
Khezami, L., & Capart, R. (2005) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2005.04.012 · Cited by 647
Cited by
Metal-organic frameworks: Challenges and opportunities for ion-exchange/sorption applications
Kumar, P., Pournara, A., Kim, K.-H., Bansal, V., Rapti, S., & Manos, M. J. (2017) · Progress in Materials Science · doi:10.1016/j.pmatsci.2017.01.002 · Cited by 423
Liu, W., Dai, X., Bai, Z., Wang, Y., Yang, Z., Zhang, L., Xu, L., Chen, L., Li, Y., Gui, D., et al. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.6b06305 · Cited by 420
Ionic metal-organic frameworks (iMOFs): Design principles and applications
Karmakar, A., Desai, A. V., & Ghosh, S. K. (2016) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2015.08.007 · Cited by 308
Cr(VI) removal via anion exchange on a silver-triazolate MOF
Li, L.-L., Feng, X.-Q., Han, R.-P., Zang, S.-Q., & Yang, G. (2017) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2016.09.029 · Cited by 308
Lithium Extraction by Emerging Metal-Organic Framework-Based Membranes
Hou, J., Zhang, H., Thornton, A. W., Hill, A. J., Wang, H., & Konstas, K. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202105991 · Cited by 248
Metadata
- Authors
- Li, X., Xu, H., Kong, F., & Wang, R.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2013-10-31
- Volume
- 52
- Issue
- 51
- Pages
- 13769-13773
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2169116687
- Cited by
- 349
- References
- 2
- FWCI
- 12.73
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: A Cationic Metal–Organic Framework Consisting of Nanoscale Cages: Capture, Separation, and Luminescent Probing of Cr2O72− through a Single‐Crystal to Single‐Crystal Process. https://app.cochat.ai/papers/10.1002/anie.201307650
- The paper
- Li, X., Xu, H., Kong, F., & Wang, R. (2013). A Cationic Metal–Organic Framework Consisting of Nanoscale Cages: Capture, Separation, and Luminescent Probing of Cr2O72− through a Single‐Crystal to Single‐Crystal Process. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201307650
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