The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Visible‐Light‐Mediated Decarboxylation/Oxidative Amidation of α‐Keto Acids with Amines under Mild Reaction Conditions Using O2
Abstract
Photochemistry has ushered in a new era in the development of chemistry, and photoredox catalysis has become a hot topic, especially over the last five years, with the combination of visible‐light photoredox catalysis and radical reactions. A novel, simple, and efficient radical oxidative decarboxylative coupling with the assistant of the photocatalyst [Ru(phen)3]Cl 2 is described. Various functional groups are well‐tolerated in this reaction and thus provides a new approach to developing advanced methods for aerobic oxidative decarboxylation. The preliminary mechanistic studies revealed that: 1) an SET process between [Ru(phen)3]2+* and aniline play an important role; 2) O 2 activation might be the rate‐determining step; and 3) the decarboxylation step is an irreversible and fast process.
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Cites
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Visible light photocatalysis as a greener approach to photochemical synthesis
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Visible‐Light Photoredox Catalysis
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Photoredox Catalysis with Visible Light
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Cited by
Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Noble, A., McCarver, S. J., & MacMillan, D. W. C. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511913h · Cited by 448
Ynamides as Racemization-Free Coupling Reagents for Amide and Peptide Synthesis
Hu, L., Xu, S., Zhao, Z., Yang, Y., Peng, Z., Yang, M., Wang, C., & Zhao, J. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b07230 · Cited by 267
Metadata
- Authors
- Liu, J., Liu, Q., Yi, H., Qin, C., Bai, R., Qi, X., Lan, Y., & Lei, A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2013-11-24
- Volume
- 53
- Issue
- 2
- Pages
- 502-506
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2159551189
- Cited by
- 451
- References
- 34
- FWCI
- 19.73
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, J., Liu, Q., Yi, H., Qin, C., Bai, R., Qi, X., Lan, Y., & Lei, A. (2014). Visible‐Light‐Mediated Decarboxylation/Oxidative Amidation of α‐Keto Acids with Amines under Mild Reaction Conditions Using O2. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201308614
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