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Monolithically Integrated Spinel MxCo3−xO4 (M=Co, Ni, Zn) Nanoarray Catalysts: Scalable Synthesis and Cation Manipulation for Tunable Low‐Temperature CH4 and CO Oxidation
Abstract
A series of large scale MxCo 3−xO 4 (M=Co, Ni, Zn) nanoarray catalysts have been cost‐effectively integrated onto large commercial cordierite monolithic substrates to greatly enhance the catalyst utilization efficiency. The monolithically integrated spinel nanoarrays exhibit tunable catalytic performance (as revealed by spectroscopy characterization and parallel first‐principles calculations) toward low‐temperature CO and CH 4 oxidation by selective cation occupancy and concentration, which lead to controlled adsorption–desorption behavior and surface defect population. This provides a feasible approach for scalable fabrication and rational manipulation of metal oxide nanoarray catalysts applicable at low temperatures for various catalytic reactions.
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Cited by
Oxygen Vacancy Promoted O2 Activation over Perovskite Oxide for Low-Temperature CO Oxidation
Yang, J., Hu, S., Fang, Y., Hoang, S., Li, L., Yang, W., Liang, Z., Wu, J., Hu, J., Xiao, W., et al. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b02408 · Cited by 601
Self-citationCheng, H., Li, M., Su, C., Li, N., & Liu, Z. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201701833 · Cited by 384
Lu, Y., Liu, T., Huang, Y.-C., Zhou, L., Li, Y., Chen, W., Yang, L., Zhou, B., Wu, Y., Kong, Z., et al. (2022) · ACS Catalysis · doi:10.1021/acscatal.2c00174 · Cited by 282
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Metadata
- Authors
- Ren, Z., Botu, V., Wang, S., Meng, Y., Song, W., Guo, Y., Ramprasad, R., Suib, S. L., & Gao, P.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-05-30
- Volume
- 53
- Issue
- 28
- Pages
- 7223-7227
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2125476510
- Cited by
- 195
- References
- 0
- FWCI
- 11.02
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Monolithically Integrated Spinel MxCo3−xO4 (M=Co, Ni, Zn) Nanoarray Catalysts: Scalable Synthesis and Cation Manipulation for Tunable Low‐Temperature CH4 and CO Oxidation. https://app.cochat.ai/papers/10.1002/anie.201403461
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- Ren, Z., Botu, V., Wang, S., Meng, Y., Song, W., Guo, Y., Ramprasad, R., Suib, S. L., & Gao, P. (2014). Monolithically Integrated Spinel MxCo3−xO4 (M=Co, Ni, Zn) Nanoarray Catalysts: Scalable Synthesis and Cation Manipulation for Tunable Low‐Temperature CH4 and CO Oxidation. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201403461
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