The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Single‐Site Copper(II) Water Oxidation Electrocatalysis: Rate Enhancements with HPO42− as a Proton Acceptor at pH 8
Abstract
The complex Cu II(Py 3 P) (1) is an electrocatalyst for water oxidation to dioxygen in H 2 PO 4−/HPO 42− buffered aqueous solutions. Controlled potential electrolysis experiments with 1 at pH 8.0 at an applied potential of 1.40 V versus the normal hydrogen electrode resulted in the formation of dioxygen (84 % Faradaic yield) through multiple catalyst turnovers with minimal catalyst deactivation. The results of an electrochemical kinetics study point to a single‐site mechanism for water oxidation catalysis with involvement of phosphate buffer anions either through atom–proton transfer in a rate‐limiting OO bond‐forming step with HPO 42− as the acceptor base or by concerted electron–proton transfer with electron transfer to the electrode and proton transfer to the HPO 42− base.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Proton-coupled electron transfer
Huynh, M. H. V., & Meyer, T. J. (2007) · Chemical Reviews · doi:10.1021/cr0500030 · Cited by 1,659
Self-citation
Cited by
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Dai, J., Zhu, Y., Chen, Y., Wen, X., Long, M., Wu, X., Hu, Z., Guan, D., Wang, X., Zhou, C., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-28843-2 · Cited by 467
Finding the Way to Solar Fuels with Dye-Sensitized Photoelectrosynthesis Cells
Brennaman, M. K., Dillon, R. J., Alibabaei, L., Gish, M. K., Dares, C. J., Ashford, D. L., House, R. L., Meyer, G. J., Papanikolas, J. M., & Meyer, T. J. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b06466 · Cited by 369
Self-citationOxidation Reactions with Bioinspired Mononuclear Non‐Heme Metal–Oxo Complexes
Engelmann, X., Monte‐Pérez, I., & Ray, K. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201600507 · Cited by 300
Polyoxometalate@Metal–Organic Framework Composites as Effective Photocatalysts
Liu, Y., Tang, C., Cheng, M., Chen, M., Chen, S., Lei, L., Chen, Y., Yi, H., Fu, Y., & Li, L. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c03866 · Cited by 253
Metadata
- Authors
- Coggins, M. K., Zhang, M., Chen, Z., Song, N., & Meyer, T. J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-09-22
- Volume
- 53
- Issue
- 45
- Pages
- 12226-12230
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2137487093
- Cited by
- 229
- References
- 1
- FWCI
- 7.86
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Single‐Site Copper(II) Water Oxidation Electrocatalysis: Rate Enhancements with HPO42− as a Proton Acceptor at pH 8. https://app.cochat.ai/papers/10.1002/anie.201407131
- The paper
- Coggins, M. K., Zhang, M., Chen, Z., Song, N., & Meyer, T. J. (2014). Single‐Site Copper(II) Water Oxidation Electrocatalysis: Rate Enhancements with HPO42− as a Proton Acceptor at pH 8. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201407131
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
