The DOI matches its Crossref record; 133 of the 133 references it cites were found in a registry or an index.
Oxidation Reactions with Bioinspired Mononuclear Non‐Heme Metal–Oxo Complexes
Abstract
The selective functionalization of strong C−H bonds and the oxidation of water by cheap and nontoxic metals are some of the key targets of chemical research today. It has been proposed that high‐valent iron‐, manganese‐, and copper‐oxo cores are involved as reactive intermediates in important oxidation reactions performed by biological systems, thus making them attractive targets for biomimetic synthetic studies. The generation and characterization of metal–oxo model complexes of iron, manganese, and copper together with detailed reactivity studies can help in understanding how the steric and electronic properties of the metal centers modulate the reactivity of the metalloenzymes. This Review provides a focused overview of the advances in the chemistry of biomimetic high‐valent metal–oxo complexes from the last 5–10 years that can be related to our understanding of biological systems.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Grätzel, M. (2001) · Nature · doi:10.1038/35104607 · Cited by 12,687
Powering the planet: Chemical challenges in solar energy utilization
Lewis, N. S., & Nocera, D. G. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0603395103 · Cited by 8,310
Beyond Oil and Gas: The Methanol Economy
Olah, G. A. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462121 · Cited by 2,431
Copper Active Sites in Biology
Solomon, E. I., Heppner, D. E., Johnston, E. M., Ginsbach, J. W., Cirera, J., Qayyum, M., Kieber-Emmons, M. T., Kjaergaard, C. H., Hadt, R. G., & Tian, L. (2014) · Chemical Reviews · doi:10.1021/cr400327t · Cited by 1,751
Water-Splitting Chemistry of Photosystem II
McEvoy, J. P., & Brudvig, G. W. (2006) · Chemical Reviews · doi:10.1021/cr0204294 · Cited by 1,550
Arndtsen, B. A., Bergman, R. G., Mobley, T. A., & Peterson, T. H. (1995) · Accounts of Chemical Research · doi:10.1021/ar00051a009 · Cited by 1,451
Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics
Rittle, J., & Green, M. T. (2010) · Science · doi:10.1126/science.1193478 · Cited by 1,368
Platinum Catalysts for the High-Yield Oxidation of Methane to a Methanol Derivative
Periana, R. A., Taube, D. J., Gamble, S., Taube, H., Satoh, T., & Fujii, H. (1998) · Science · doi:10.1126/science.280.5363.560 · Cited by 1,338
A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II
Duan, L., Bozoglian, F., Mandal, S., Stewart, B., Privalov, T., Llobet, A., & Sun, L. (2012) · Nature Chemistry · doi:10.1038/nchem.1301 · Cited by 1,257
Theoretical Perspective on the Structure and Mechanism of Cytochrome P450 Enzymes
Shaik, S., Kumar, D., de Visser, S. P., Altun, A., & Thiel, W. (2005) · Chemical Reviews · doi:10.1021/cr030722j · Cited by 1,236
Cited by
Computational Approach to Molecular Catalysis by 3d Transition Metals: Challenges and Opportunities
Vogiatzis, K. D., Polynski, M. V., Kirkland, J. K., Townsend, J., Hashemi, A., Liu, C., & Pidko, E. A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00361 · Cited by 423
Guo, M., Corona, T., Ray, K., & Nam, W. (2019) · ACS Central Science · doi:10.1021/acscentsci.8b00698 · Cited by 401
Self-citationCheignon, C., Jones, M., Atrián-Blasco, E., Kieffer, I., Faller, P., Collin, F., & Hureau, C. (2017) · Chemical Science · doi:10.1039/c7sc00809k · Cited by 132
Nandy, A., Zhu, J., Janet, J. P., Duan, C., Getman, R. B., & Kulik, H. J. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b02165 · Cited by 91
Metadata
- Authors
- Engelmann, X., Monte‐Pérez, I., & Ray, K.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-06-16
- Volume
- 55
- Issue
- 27
- Pages
- 7632-7649
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2413395909
- Cited by
- 300
- References
- 133
- FWCI
- 15.46
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Oxidation Reactions with Bioinspired Mononuclear Non‐Heme Metal–Oxo Complexes. https://app.cochat.ai/papers/10.1002/anie.201600507
- The paper
- Engelmann, X., Monte‐Pérez, I., & Ray, K. (2016). Oxidation Reactions with Bioinspired Mononuclear Non‐Heme Metal–Oxo Complexes. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201600507
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
