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Solvent Effects in Acid‐Catalyzed Biomass Conversion Reactions
Open accessAbstract
Reaction kinetics were studied to quantify the effects of polar aprotic organic solvents on the acid‐catalyzed conversion of xylose into furfural. A solvent of particular importance is γ‐valerolactone (GVL), which leads to significant increases in reaction rates compared to water in addition to increased product selectivity. GVL has similar effects on the kinetics for the dehydration of 1,2‐propanediol to propanal and for the hydrolysis of cellobiose to glucose. Based on results obtained for homogeneous Brønsted acid catalysts that span a range of p Ka values, we suggest that an aprotic organic solvent affects the reaction kinetics by changing the stabilization of the acidic proton relative to the protonated transition state. This same behavior is displayed by strong solid Brønsted acid catalysts, such as H‐mordenite and H‐beta.
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Cited by
Organic Solvent Effects in Biomass Conversion Reactions
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Petridis, L., & Smith, J. C. (2018) · Nature Reviews Chemistry · doi:10.1038/s41570-018-0050-6 · Cited by 228
Chen, Z., Bai, X., A, L., & Wan, C. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b02541 · Cited by 221
Influence of solvent structure and hydrogen bonding on catalysis at solid–liquid interfaces
Potts, D. S., Bregante, D. T., Adams, J. S., Torres, C., & Flaherty, D. W. (2021) · Chemical Society Reviews · doi:10.1039/d1cs00539a · Cited by 190
Hydrothermal carbonization and liquefaction for sustainable production of hydrochar and aromatics
Cao, Y., He, M., Dutta, S., Luo, G., Zhang, S., & Tsang, D. C. W. (2021) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2021.111722 · Cited by 175
Metadata
- Authors
- Mellmer, M. A., Sener, C., Gallo, J. M. R., Luterbacher, J. S., Alonso, D. M., & Dumesic, J. A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-09-11
- Volume
- 53
- Issue
- 44
- Pages
- 11872-11875
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2106108754
- Cited by
- 451
- References
- 1
- FWCI
- 12.58
- Type
- journal article
- Language
- en
- Open access
- green
- Licence
- onlinelibrary.wiley.com/termsAndConditions#vor (vor)
- doi.wiley.com/10.1002/tdm_license_1.1 (tdm)
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- Mellmer, M. A., Sener, C., Gallo, J. M. R., Luterbacher, J. S., Alonso, D. M., & Dumesic, J. A. (2014). Solvent Effects in Acid‐Catalyzed Biomass Conversion Reactions. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201408359
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
