Catalytic consequences of acid strength in the conversion of methanol to dimethyl ether
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At Brønsted acid sites, DME can be formed via a concerted and a stepwise mechanism.
“AtBrønstedacidsites,DMEcanbeformedviatheconcertedandthestepwisemechanism.”
From Reactivity of Surface Lewis and Brønsted Acid Sites in Zeolite Catalysis: A Computational Case Study of DME Synthesis Using H-SSZ-13 (2022) · cites this paper as [91]
In the concerted mechanism, two adsorbed MeOH react directly.
“Intheconcertedmechanism,twoadsorbedMeOH reactdirectly.”
From Reactivity of Surface Lewis and Brønsted Acid Sites in Zeolite Catalysis: A Computational Case Study of DME Synthesis Using H-SSZ-13 (2022) · cites this paper as [91]
In the stepwise mechanism, DME is formed through reaction of a surface methoxyspecies (SMS) with MeOH.
“Inthestepwisemechanism,DMEisformed throughreactionofasurfacemethoxyspecies(SMS)with MeOH.”
From Reactivity of Surface Lewis and Brønsted Acid Sites in Zeolite Catalysis: A Computational Case Study of DME Synthesis Using H-SSZ-13 (2022) · cites this paper as [91]
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- Authors
- Carr, R. T., Neurock, M., & Iglesia, E.
- Affiliations
- University of California, Berkeley (US)
- University of Virginia (US)
- ORCID
- Neurock, Matthew
- Venue
- Journal of Catalysis
- Publisher
- Elsevier BV
- Published
- 2011-02-14
- Volume
- 278
- Issue
- 1
- Pages
- 78-93
- ISSN
- 0021-9517 (ISSN-L)
- OpenAlex
- W2115127541
- Cited by
- 203
- References
- 57
- Citations by year
- 2026: 8 · 2025: 7 · 2024: 12 · 2023: 18 · 2022: 7 · 2021: 13 · 2020: 25 · 2019: 13 · 2018: 11 · 2017: 18 · 2016: 13 · 2015: 12 · 2014: 21 · 2013: 13 · 2012: 8
- FWCI
- 7.23
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Catalysis (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Polyoxometalates: Synthesis and Applications
- Physical Sciences › Chemical Engineering › Catalysis › Catalysis and Oxidation Reactions
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Keywords
- methanol dehydration, dimethyl ether synthesis, acid strength, deprotonation energy, Keggin-type polyoxometalates, heterogeneous acid catalysis, methyl cation, reaction mechanism, rate constants, confinement effects, transition state stabilization, reaction intermediates
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