The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Photoelectrochemical Hydrogen Production in Alkaline Solutions Using Cu2O Coated with Earth‐Abundant Hydrogen Evolution Catalysts
Open accessAbstract
The splitting of water into hydrogen and oxygen molecules using sunlight is an attractive method for solar energy storage. Until now, photoelectrochemical hydrogen evolution is mostly studied in acidic solutions, in which the hydrogen evolution is more facile than in alkaline solutions. Herein, we report photoelectrochemical hydrogen production in alkaline solutions, which are more favorable than acidic solutions for the complementary oxygen evolution half‐reaction. We show for the first time that amorphous molybdenum sulfide is a highly active hydrogen evolution catalyst in basic medium. The amorphous molybdenum sulfide catalyst and a Ni–Mo catalyst are then deposited on surface‐protected cuprous oxide photocathodes to catalyze sunlight‐driven hydrogen production in 1 M KOH. The photocathodes give photocurrents of −6.3 mA cm−2 at the reversible hydrogen evolution potential, the highest yet reported for a metal oxide photocathode using an earth‐abundant hydrogen evolution reaction catalyst.
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Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution
Morales-Guio, C. G., Stern, L.-A., & Hu, X. (2014) · Chemical Society Reviews · doi:10.1039/c3cs60468c · Cited by 2,437
Self-citationLaursen, A. B., Kegnæs, S., Dahl, S., & Chorkendorff, I. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02618j · Cited by 1,348
Developments and perspectives of oxide-based catalysts for the oxygen evolution reaction
Fabbri, E., Habereder, A., Waltar, K., Kötz, R., & Schmidt, T. J. (2014) · Catal. Sci. Technol. · doi:10.1039/c4cy00669k · Cited by 1,303
Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts
Merki, D., & Hu, X. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01970h · Cited by 1,172
Self-citationSeger, B., Laursen, A. B., Vesborg, P. C. K., Pedersen, T., Hansen, O., Dahl, S., & Chorkendorff, I. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201203585 · Cited by 306
Growth and Activation of an Amorphous Molybdenum Sulfide Hydrogen Evolving Catalyst
Vrubel, H., & Hu, X. (2013) · ACS Catalysis · doi:10.1021/cs400441u · Cited by 292
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Cited by
Visible-light driven heterojunction photocatalysts for water splitting – a critical review
Moniz, S. J. A., Shevlin, S. A., Martin, D. J., Guo, Z.-X., & Tang, J. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03271c · Cited by 2,363
Boosting the performance of Cu2O photocathodes for unassisted solar water splitting devices
Pan, L., Kim, J. H., Mayer, M. T., Son, M.-K., Ummadisingu, A., Lee, J. S., Hagfeldt, A., Luo, J., & Grätzel, M. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0077-6 · Cited by 733
Self-citationXu, R., Wu, R., Shi, Y., Zhang, J., & Zhang, B. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.04.006 · Cited by 425
Bipolar Membrane‐Assisted Solar Water Splitting in Optimal pH
Luo, J., Vermaas, D. A., Bi, D., Hagfeldt, A., Smith, W. A., & Grätzel, M. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201600100 · Cited by 205
Self-citationSustainability analysis of different hydrogen production options using hesitant fuzzy AHP
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Metadata
- Authors
- Morales‐Guio, C. G., Liardet, L., Mayer, M. T., Tilley, S. D., Grätzel, M., & Hu, X.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-11-17
- Volume
- 54
- Issue
- 2
- Pages
- 664-667
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2166081330
- Cited by
- 235
- References
- 8
- FWCI
- 9.17
- Type
- journal article
- Language
- en
- Open access
- green
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- Morales‐Guio, C. G., Liardet, L., Mayer, M. T., Tilley, S. D., Grätzel, M., & Hu, X. (2015). Photoelectrochemical Hydrogen Production in Alkaline Solutions Using Cu2O Coated with Earth‐Abundant Hydrogen Evolution Catalysts. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201410569
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