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Defect‐Engineered Metal–Organic Frameworks
Open accessAbstract
Defect engineering in metal–organic frameworks (MOFs) is an exciting concept for tailoring material properties, which opens up novel opportunities not only in sorption and catalysis, but also in controlling more challenging physical characteristics such as band gap as well as magnetic and electrical/conductive properties. It is challenging to structurally characterize the inherent or intentionally created defects of various types, and there have so far been few efforts to comprehensively discuss these issues. Based on selected reports spanning the last decades, this Review closes that gap by providing both a concise overview of defects in MOFs, or more broadly coordination network compounds (CNCs), including their classification and characterization, together with the (potential) applications of defective CNCs/MOFs. Moreover, we will highlight important aspects of “defect‐engineering” concepts applied for CNCs, also in comparison with relevant solid materials such as zeolites or COFs. Finally, we discuss the future potential of defect‐engineered CNCs.
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Cited by
Defect Engineering on Electrode Materials for Rechargeable Batteries
Zhang, Y., Tao, L., Xie, C., Wang, D., Zou, Y., Chen, R., Wang, Y., Jia, C., & Wang, S. (2020) · Advanced Materials · doi:10.1002/adma.201905923 · Cited by 1,019
Single Pt Atoms Confined into a Metal–Organic Framework for Efficient Photocatalysis
Fang, X., Shang, Q., Wang, Y., Jiao, L., Yao, T., Li, Y., Zhang, Q., Luo, Y., & Jiang, H. (2018) · Advanced Materials · doi:10.1002/adma.201705112 · Cited by 837
Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends
Yuan, S., Qin, J.-S., Lollar, C. T., & Zhou, H.-C. (2018) · ACS Central Science · doi:10.1021/acscentsci.8b00073 · Cited by 561
Zhu, Y., Ciston, J., Zheng, B., Miao, X., Czarnik, C., Pan, Y., Sougrat, R., Lai, Z., Hsiung, C.-E., Yao, K., et al. (2017) · Nature Materials · doi:10.1038/nmat4852 · Cited by 429
Metal organic framework based catalysts for CO2 conversion
Maina, J. W., Pozo-Gonzalo, C., Kong, L., Schütz, J., Hill, M., & Dumée, L. F. (2017) · Materials Horizons · doi:10.1039/c6mh00484a · Cited by 423
Metadata
- Authors
- Fang, Z., Bueken, B., De Vos, D. E., & Fischer, R. A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-06-03
- Volume
- 54
- Issue
- 25
- Pages
- 7234-7254
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W1943588217
- Cited by
- 1,252
- References
- 0
- FWCI
- 36.12
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Fang, Z., Bueken, B., De Vos, D. E., & Fischer, R. A. (2015). Defect‐Engineered Metal–Organic Frameworks. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201411540
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