The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Electrodeposited Cobalt‐Phosphorous‐Derived Films as Competent Bifunctional Catalysts for Overall Water Splitting
Abstract
One of the challenges to realize large‐scale water splitting is the lack of active and low‐cost electrocatalysts for its two half reactions: H 2 and O 2 evolution reactions (HER and OER). Herein, we report that cobalt‐phosphorous‐derived films (Co‐P) can act as bifunctional catalysts for overall water splitting. The as‐prepared Co‐P films exhibited remarkable catalytic performance for both HER and OER in alkaline media, with a current density of 10 mA cm−2 at overpotentials of −94 mV for HER and 345 mV for OER and Tafel slopes of 42 and 47 mV/dec, respectively. They can be employed as catalysts on both anode and cathode for overall water splitting with 100 % Faradaic efficiency, rivalling the integrated performance of Pt and IrO 2. The major composition of the as‐prepared and post‐HER films are metallic cobalt and cobalt phosphide, which partially evolved to cobalt oxide during OER.
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Cites
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402646 · Cited by 1,240
First-row transition metal dichalcogenide catalysts for hydrogen evolution reaction
Kong, D., Cha, J. J., Wang, H., Lee, H. R., & Cui, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee42413h · Cited by 1,031
Merki, D., Vrubel, H., Rovelli, L., Fierro, S., & Hu, X. (2012) · Chemical Science · doi:10.1039/c2sc20539d · Cited by 941
Xing, Z., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Advanced Materials · doi:10.1002/adma.201401692 · Cited by 835
Sun, Y., Liu, C., Grauer, D. C., Yano, J., Long, J. R., Yang, P., & Chang, C. J. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4094764 · Cited by 556
Self-citationHigh-Efficiency Electrochemical Hydrogen Evolution Catalyzed by Tungsten Phosphide Submicroparticles
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Cited by
Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting
Roger, I., Shipman, M. A., & Symes, M. D. (2017) · Nature Reviews Chemistry · doi:10.1038/s41570-016-0003 · Cited by 3,503
Anantharaj, S., Ede, S. R., Sakthikumar, K., Karthick, K., Mishra, S., & Kundu, S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02479 · Cited by 2,503
Recent Progress in Cobalt‐Based Heterogeneous Catalysts for Electrochemical Water Splitting
Wang, J., Cui, W., Liu, Q., Xing, Z., Asiri, A. M., & Sun, X. (2016) · Advanced Materials · doi:10.1002/adma.201502696 · Cited by 2,446
Yan, Y., Xia, B. Y., Zhao, B., & Wang, X. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta08075h · Cited by 1,368
Ultrathin metal-organic framework array for efficient electrocatalytic water splitting
Duan, J., Chen, S., & Zhao, C. (2017) · Nature Communications · doi:10.1038/ncomms15341 · Cited by 1,319
Metadata
- Authors
- Jiang, N., You, B., Sheng, M., & Sun, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-04-20
- Volume
- 54
- Issue
- 21
- Pages
- 6251-6254
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2164017033
- Cited by
- 844
- References
- 8
- FWCI
- 37.44
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jiang, N., You, B., Sheng, M., & Sun, Y. (2015). Electrodeposited Cobalt‐Phosphorous‐Derived Films as Competent Bifunctional Catalysts for Overall Water Splitting. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201501616
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