Fe, Co, and Ni ions promote the catalytic activity of amorphous molybdenum sulfide films for hydrogen evolution
Open accessAbstract
Molybdenum sulfide materials have been shown as promising non-precious catalysts for hydrogen evolution. This paper describes the study of the promotional effects of certain transition metal ions on the activity of amorphous MoS3 films. Ternary metal sulfide films, M–MoS3 (M = Mn, Fe, Co, Ni, Cu, Zn), have been prepared by cyclic voltammetry of aqueous solutions containing MCl2 and (NH4)2[MoS4]. Whereas the Mn–, Cu–, and Zn–MoS3 films show similar or only slightly higher catalytic activity as the MoS3 film, the Fe–, Co–, and Ni–MoS3 films are significantly more active. The promotional effects of Fe, Co, and Ni ions exist under both acidic and neutral conditions, but the effects are more pronounced under neutral conditions. Up to a 12-fold increase in exchange current density and a 10-fold increase in the current density at an overpotential of 150 mV are observed at pH = 7. It is shown that Fe, Co, and Ni ions promote the growth of the MoS3 films, resulting a high surface area and a higher catalyst loading. These changes are the main contributors to the enhanced activity at pH = 0. However, at pH = 7, Fe, Co, and Ni ions appear to also increase the intrinsic activity of the MoS3 film.
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Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100 · see citing works
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Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114 · see citing works
“7 further doped with transition metals such as Fe, Co and Ni, improving their activity significantly (45).”
The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
Chhowalla, M., Shin, H. S., Eda, G., Li, L.-J., Loh, K. P., & Zhang, H. (2013) · Nature Chemistry · doi:10.1038/nchem.1589 · Cited by 10,034 · see citing works
Noble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955 · see citing works
McCrory, C. C. L., Jung, S., Ferrer, I. M., Chatman, S. M., Peters, J. C., & Jaramillo, T. F. (2015) · Journal of the American Chemical Society · doi:10.1021/ja510442p · Cited by 4,145 · see citing works
Lukowski, M. A., Daniel, A. S., Meng, F., Forticaux, A., Li, L., & Jin, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja404523s · Cited by 3,341 · see citing works
Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234 · see citing works
Hydrogen evolution by a metal-free electrocatalyst
Zheng, Y., Jiao, Y., Zhu, Y., Li, L. H., Han, Y., Chen, Y., Du, A., Jaroniec, M., & Qiao, S. Z. (2014) · Nature Communications · doi:10.1038/ncomms4783 · Cited by 2,236 · see citing works
Metal-free catalysts for oxygen reduction reaction.
Dai, L., Xue, Y.-H., Qu, L., Choi, H.-J., & Baek, J.-B. (2015) · Chemical Reviews · doi:10.1021/cr5003563 · Cited by 2,127 · see citing works
Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis
Song, F., & Hu, X.-L. (2014) · Nature Communications · doi:10.1038/ncomms5477 · Cited by 2,050 · see citing works
Self-citationZheng, Y., Jiao, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201407031 · Cited by 2,046 · see citing works
Emerging Two-Dimensional Nanomaterials for Electrocatalysis
Jin, H., Guo, C., Liu, X., Liu, J., Vasileff, A., Jiao, Y., Zheng, Y., & Qiao, S. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00689 · Cited by 2,030 · see citing works
Catalyzing the hydrogen evolution reaction (HER) with molybdenum sulfide nanomaterials
Benck, J. D., Hellstern, T. R., Kibsgaard, J., Chakthranont, P., & Jaramillo, T. F. (2014) · ACS Catalysis · doi:10.1021/cs500923c · Cited by 1,617 · see citing works
Nanoarchitectonics for Transition‐Metal‐Sulfide‐Based Electrocatalysts for Water Splitting
Guo, Y., Park, T., Yi, J. W., Henzie, J., Kim, J., Wang, Z., Jiang, B., Bando, Y., Sugahara, Y., Tang, J., et al. (2019) · Advanced Materials · doi:10.1002/adma.201807134 · Cited by 1,402 · see citing works
Kong, D., Wang, H., Lu, Z., & Cui, Y. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501497n · Cited by 1,392 · see citing works
Defect Chemistry of Nonprecious‐Metal Electrocatalysts for Oxygen Reactions
Yan, D., Li, Y., Huo, J., Chen, R., Dai, L., & Wang, S. (2017) · Advanced Materials · doi:10.1002/adma.201606459 · Cited by 1,594 · see citing works
Molybdenum Boride and Carbide Catalyze Hydrogen Evolution in both Acidic and Basic Solutions
Vrubel, H., & Hu, X. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201207111 · Cited by 1,305 · see citing works
Self-citationBenck, J. D., Chen, Z., Kuritzky, L. Y., Forman, A. J., & Jaramillo, T. F. (2012) · ACS Catalysis · doi:10.1021/cs300451q · Cited by 1,091 · see citing works
Liu, Q., Tian, J.-Q., Cui, W., Jiang, P., Cheng, N., Asiri, A. M., & Sun, X.-P. (2014) · Angewandte Chemie · doi:10.1002/anie.201404161 · Cited by 1,057 · see citing works
Efficient hydrogen production on MoNi4 electrocatalysts with fast water dissociation kinetics
Zhang, J., Wang, T., Liu, P., Liao, Z., Liu, S., Zhuang, X.-D., Chen, M.-W., Zschech, E., & Feng, X.-L. (2017) · Nature Communications · doi:10.1038/ncomms15437 · Cited by 1,047 · see citing works
Ultrathin cobalt-manganese layered double hydroxide is an efficient oxygen evolution catalyst.
Song, F., & Hu, X.-L. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5096733 · Cited by 1,047 · see citing works
Self-citationFirst-row transition metal dichalcogenide catalysts for hydrogen evolution reaction
Kong, D., Cha, J. J., Wang, H., Lee, H. R., & Cui, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee42413h · Cited by 1,031 · see citing works
Zou, X., Huang, X., Goswami, A., Silva, R., Sathe, B. R., Mikmeková, E., & Asefa, T. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201311111 · Cited by 979 · see citing works
Zheng, Y., Jiao, Y., Li, L. H., Xing, T., Chen, Y. I., Jaroniec, M., & Qiao, S. (2014) · ACS Nano · doi:10.1021/nn501434a · Cited by 1,062 · see citing works
Deng, J., Li, H., Xiao, J., Tu, Y., Deng, D., Yang, H., Tian, H., Li, J., Ren, P., & Bao, X. (2015) · Energy & Environmental Science · doi:10.1039/c5ee00751h · Cited by 1,339 · see citing works
Gao, M., Liang, J., Zheng, Y., Xu, Y., Jiang, J., Gao, Q., Li, J., & Yu, S. (2015) · Nature Communications · doi:10.1038/ncomms6982 · Cited by 1,025 · see citing works
Yan, Y., Xia, B., Xu, Z., & Wang, X. (2014) · ACS Catalysis · doi:10.1021/cs500070x · Cited by 868 · see citing works
Highly active and durable nanostructured molybdenum carbide electrocatalysts for hydrogen production
Chen, W., Wang, C., Sasaki, K., Marinković, N., Xu, W., Muckerman, J. T., Zhu, Y., & Adžić, R. R. (2013) · Energy & Environmental Science · doi:10.1039/c2ee23891h · Cited by 934 · see citing works
Kibsgaard, J., Jaramillo, T. F., & Besenbacher, F. (2014) · Nature Chemistry · doi:10.1038/nchem.1853 · Cited by 839 · see citing works
Tian, J., Liu, Q., Cheng, N., Asiri, A. M., & Sun, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201403842 · Cited by 851 · see citing works
Xing, Z., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Advanced Materials · doi:10.1002/adma.201401692 · Cited by 835 · see citing works
Jiang, N., You, B., Sheng, M., & Sun, Y.-J. (2015) · Angewandte Chemie · doi:10.1002/anie.201501616 · Cited by 826 · see citing works
Voiry, D., Fullon, R., Yang, J., de Carvalho Castro e Silva, C., Kappera, R., Bozkurt, I., Kaplan, D., Lagos, M. J., Batson, P. E., Gupta, G., et al. (2016) · Nature Materials · doi:10.1038/nmat4660 · Cited by 824 · see citing works
Electrochemistry of Nanostructured Layered Transition-Metal Dichalcogenides.
Chia, X.-Y., Eng, A. Y. S., Ambrosi, A., Tan, S., & Pumera, M. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00287 · Cited by 792 · see citing works
Mechanism of Hydrogen Evolution Reaction on 1T-MoS 2 from First Principles
Tang, Q. H., & Jiang, D. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b01211 · Cited by 864 · see citing works
McFarland, E., & Metiu, H. (2013) · Chemical Reviews · doi:10.1021/cr300418s · Cited by 765 · see citing works
Mixed Metal Sulfides for Electrochemical Energy Storage and Conversion
Yu, X.-Y., & Lou, X. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201701592 · Cited by 742 · see citing works
Layer-Dependent Electrocatalysis of MoS<sub>2</sub> for Hydrogen Evolution
Yu, Y., Huang, S.-Y., Li, Y., Steinmann, S. N., Yang, W., & Cao, L. (2014) · Nano Letters · doi:10.1021/nl403620g · Cited by 740 · see citing works
Recent Development in Hydrogen Evolution Reaction Catalysts and Their Practical Implementation
Vesborg, P. C. K., Seger, B., & Chorkendorff, I. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b00306 · Cited by 726 · see citing works
Deng, J., Ren, P., Deng, D., Yu, L., Yang, F., & Bao, X. (2014) · Energy & Environmental Science · doi:10.1039/c4ee00370e · Cited by 934 · see citing works
Chandrasekaran, S., Yao, L. J., Deng, L., Bowen, C., Zhang, Y., Chen, S., Lin, Z., Peng, F., & Zhang, P. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00664d · Cited by 1,225 · see citing works
Highly active hydrogen evolution catalysis from metallic WS <sub>2</sub> nanosheets
Lukowski, M. A., Daniel, A. S., English, C. R., Meng, F., Forticaux, A., Hamers, R. J., & Jin, S. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01329h · Cited by 709 · see citing works
MoS <sub>2</sub> Formed on Mesoporous Graphene as a Highly Active Catalyst for Hydrogen Evolution
Liao, L., Zhu, J., Bian, X., Zhu, L., Scanlon, M. D., Girault, H. H., & Liu, B. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201300318 · Cited by 705 · see citing works
Wang, H., Kong, D., Johanes, P., Cha, J. J., Zheng, G., Yan, K., Liu, N., & Cui, Y. (2013) · Nano Letters · doi:10.1021/nl401944f · Cited by 693 · see citing works
Gao, M.-R., Chan, M. K. Y., & Sun, Y. (2015) · Nature Communications · doi:10.1038/ncomms8493 · Cited by 736 · see citing works
Long, X., Li, G., Wang, Z., Zhu, H., Zhang, T., Xiao, S., Guo, W., & Yang, S. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b07728 · Cited by 657 · see citing works
Electrocatalysts for the generation of hydrogen, oxygen and synthesis gas
Sapountzi, F. M., Gracia, J. M., Weststrate, C. J., Fredriksson, H. O. A., & Niemantsverdriet, J. W. (2016) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2016.09.001 · Cited by 772 · see citing works
“8 times larger current densities were observed in acidic environment) the HER activity of amorphous MoSx films [329].”
BackgroundWang, H., Lu, Z., Kong, D., Sun, J., Hymel, T. M., & Cui, Y. (2014) · ACS Nano · doi:10.1021/nn500959v · Cited by 611 · see citing works
CoP‐Doped MOF‐Based Electrocatalyst for pH‐Universal Hydrogen Evolution Reaction
Liu, T., Li, P., Yao, N., Cheng, G., Chen, S., Luo, W., & Yin, Y. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201901409 · Cited by 606 · see citing works
Wang, H., Tsai, C., Kong, D., Chan, K., Abild‐Pedersen, F., Nørskov, J. K., & Cui, Y. (2015) · Nano Research · doi:10.1007/s12274-014-0677-7 · Cited by 664 · see citing works
Amorphous molybdenum sulfides as hydrogen evolution catalysts.
Morales-Guio, C., & Hu, X.-L. (2014) · Accounts of Chemical Research · doi:10.1021/ar5002022 · Cited by 558 · see citing works
Self-citationSun, Y., Liu, C., Grauer, D. C., Yano, J., Long, J. R., Yang, P., & Chang, C. J. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4094764 · Cited by 556 · see citing works
Li, J., Yan, M., Zhou, X., Huang, Z., Xia, Z., Chang, C., Ma, Y., & Qu, Y. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201601420 · Cited by 556 · see citing works
Symes, M., & Cronin, L. (2013) · Nature Chemistry · doi:10.1038/nchem.1621 · Cited by 528 · see citing works
Ding, Q., Song, B., Xu, P., & Jin, S. (2016) · Chem · doi:10.1016/j.chempr.2016.10.007 · Cited by 573 · see citing works
Yan, X., Tian, L., He, M., & Chen, X. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b02205 · Cited by 564 · see citing works
Thoi, V. S., Sun, Y.-J., Long, J. R., & Chang, C. J. (2013) · Chemical Society Reviews · doi:10.1039/c2cs35272a · Cited by 501 · see citing works
Deng, J., Li, H., Wang, S.-H., Ding, D., Chen, M., Liu, C., Tian, Z., Novoselov, K. S., Ma, C., Deng, D., et al. (2017) · Nature Communications · doi:10.1038/ncomms14430 · Cited by 570 · see citing works
Electrochemical Synthesis of Photoelectrodes and Catalysts for Use in Solar Water Splitting.
Kang, D., Kim, T. W., Kubota, S., Cardiel, A. C., Cha, H., & Choi, K.-S. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00498 · Cited by 499 · see citing works
Kuang, M., Wang, Q.-H., Han, P., & Zheng, G. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700193 · Cited by 475 · see citing works
Zhao, Y., Zhao, F., Wang, X., Xu, C., Zhang, Z., Shi, G., & Qu, L. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201409080 · Cited by 518 · see citing works
Nanostructured Metal Chalcogenides for Energy Storage and Electrocatalysis
Zhang, Y., Zhou, Q., Zhu, J., Yan, Q., Dou, S. X., & Sun, W. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201702317 · Cited by 520 · see citing works
Peng, S., Li, L., Han, X., Sun, W., Srinivasan, M., Mhaisalkar, S. G., Cheng, F., Yan, Q., Chen, J., & Ramakrishna, S. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201408876 · Cited by 428 · see citing works
Precious Metal Free Hydrogen Evolution Catalyst Design and Application
Feidenhans'l, A. A., Regmi, Y. N., Wei, C., Xia, D., Kibsgaard, J., & King, L. A. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00712 · Cited by 516 · see citing works
Miao, J., Xiao, F., Yang, H. B., Khoo, S. Y., Chen, J., Fan, Z., Hsu, Y., Chen, H. M., Zhang, H., & Liu, B. (2015) · Science Advances · doi:10.1126/sciadv.1500259 · Cited by 475 · see citing works
“The increase in Tafel slopes is due to the much lower proton concentration (~1 × 10 M, standard conditions) in neutral electrolytes than in acidic solutions, in which electrochemical hydrogen adsorption (Volmer reaction) and electrochemical desorption (Heyrovsky reaction) processes proceed at comparable rates (39).”
BackgroundMethodResultInfluentialHu, J., Zhang, C.-X., Jiang, L., Lin, H., An, Y.-M., Zhou, D., Leung, M., & Yang, S.-H. (2017) · Joule · doi:10.1016/j.joule.2017.07.011 · Cited by 423 · see citing works
Dai, X., Du, K., Li, Z., Liu, M., Ma, Y., Sun, H., Zhang, X., & Yang, Y. K. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b08420 · Cited by 473 · see citing works
Jiang, N., Tang, Q., Sheng, M., You, B., Jiang, D.-E., & Sun, Y.-J. (2016) · Catalysis Science & Technology · doi:10.1039/c5cy01111f · Cited by 409 · see citing works
Nanostructured materials on 3D nickel foam as electrocatalysts for water splitting
Chaudhari, N. K., Jin, H., Kim, B., & Lee, K. (2017) · Nanoscale · doi:10.1039/c7nr04187j · Cited by 584 · see citing works
Jia, J. F., Xiong, T., Zhao, L., Wang, F., Liu, H., Hu, R., Zhou, J. F., Zhou, W., & Chen, S. W. (2017) · ACS Nano · doi:10.1021/acsnano.7b06607 · Cited by 469 · see citing works
Non-noble Metal Electrocatalysts for the Hydrogen Evolution Reaction in Water Electrolysis
Wu, H., Feng, C., Zhang, L., Zhang, J., & Wilkinson, D. P. (2021) · Electrochemical Energy Reviews · doi:10.1007/s41918-020-00086-z · Cited by 486 · see citing works
“6b)] showed Tafel slopes of 58, 76, 118, 132 and 231 mV dec−1 for Co2P@NPG, Co2P clusters, NPG, NG and PG electrocatalysts, respectively, suggesting that these two catalysts followed the Volmer–Heyrovsky reaction during HER and that the rate-determining step was the slow combination of hydronium ions with hydrogen ato…”
BackgroundZhang, H., Yu, L., Chen, T., Zhou, W., & Lou, X. W. (. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201807086 · Cited by 395 · see citing works
Wang, T., Liu, L., Zhu, Z., Papakonstantinou, P., Hu, J., Liu, H., & Li, M. (2013) · Energy Environ. Sci. · doi:10.1039/c2ee23513g · Cited by 393 · see citing works
Yu, L., Xia, B. Y., Wang, X., & Lou, X. W. (2016) · Advanced Materials · doi:10.1002/adma.201504024 · Cited by 383 · see citing works
Shan, X., Liu, J., Mu, H., Xiao, Y.-Y., Mei, B.-B., Liu, W.-G., Lin, G., Jiang, Z., Wen, L.-P., & Jiang, L. (2019) · Angewandte Chemie · doi:10.1002/ange.201911617 · Cited by 374
Ding, Q., Meng, F., English, C., Cabán-Acevedo, M., Shearer, M. J., Liang, D., Daniel, A. S., Hamers, R., & Jin, S. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5025673 · Cited by 374 · see citing works
Heterojunction catalyst in electrocatalytic water splitting
Li, Z., Hu, M., Wang, P., Liu, J., Yao, J., & Li, C. (2021) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2021.213953 · Cited by 458 · see citing works
Boundary activated hydrogen evolution reaction on monolayer MoS2
Zhu, J., Wang, Z., Dai, H., Wang, Q., Yang, R., Yu, H., Liao, M., Zhang, J., Chen, W., Wei, Z., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-09269-9 · Cited by 402 · see citing works
Wang, X., Xu, Y., Rao, H., Xu, W., Chen, H., Zhang, W., Kuang, D., & Su, C. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03801d · Cited by 470 · see citing works
Anjum, M., Jeong, H., Lee, M.-H., Shin, H., & Lee, J. S. (2018) · Advances in Materials · doi:10.1002/adma.201707105 · Cited by 364 · see citing works
Xu, J., Zhang, J., Zhang, W., & Lee, C. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700571 · Cited by 409 · see citing works
Wu, Z.-Z., Fang, B., Wang, Z., Wang, C.-L., Liu, Z.-H., Liu, F., Wang, W., Alfantazi, A., Wang, D.-Z., & Wilkinson, D. (2013) · ACS Catalysis · doi:10.1021/cs400384h · Cited by 359 · see citing works
Ling, C., Shi, L., Ouyang, Y., & Wang, J. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b03972 · Cited by 355 · see citing works
Enabling Silicon for Solar-Fuel Production
Sun, K., Shen, S., Liang, Y., Burrows, P. E., Mao, S. S., & Wang, D. (2014) · Chemical Reviews · doi:10.1021/cr300459q · Cited by 393 · see citing works
Huang, Y., Hu, L., Liu, R., Hu, Y., Xiong, T., Qiu, W., Balogun, M.-S. (. T., Pan, A., & Tong, Y. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.03.037 · Cited by 336 · see citing works
Vrubel, H., Moehl, T., Grätzel, M., & Hu, X. (2013) · Chemical Communications · doi:10.1039/c3cc45416a · Cited by 335 · see citing works
Self-citationHu, J., Huang, B., Zhang, C., Wang, Z., An, Y., Zhou, D., Lin, H., Leung, M. K. H., & Yang, S. (2017) · Energy & Environmental Science · doi:10.1039/c6ee03629e · Cited by 334 · see citing works
Cui, W., Cheng, N., Liu, Q., Ge, C., Asiri, A. M., & Sun, X.-P. (2014) · ACS Catalysis · doi:10.1021/cs5005294 · Cited by 333 · see citing works
Zhou, X., Liu, Y., Ju, H., Pan, B., Zhu, J., Ding, T., Wang, C., & Yang, Q. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b05006 · Cited by 354 · see citing works
Li, Y., Zhang, H., Jiang, M. Z., Kuang, Y., Sun, X., & Duan, X. (2016) · Nano Research · doi:10.1007/s12274-016-1112-z · Cited by 374 · see citing works
Biomass-derived electrocatalytic composites for hydrogen evolution
Chen, W.-F., Iyer, S., Iyer, S., Sasaki, K., Wang, C.-H., Zhu, Y.-M., Muckerman, J., & Fujita, E. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40596f · Cited by 324 · see citing works
Xiao, W., Liu, P., Zhang, J., Song, W., Feng, Y. P., Gao, D., & Ding, J. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201602086 · Cited by 368 · see citing works
Boosting hydrogen evolution on MoS2 via co-confining selenium in surface and cobalt in inner layer
Zheng, Z., Yu, L., Gao, M., Chen, X., Zhou, W., Ma, C., Wu, L.-H., Zhu, J.-F., Meng, X.-Y., Hu, J., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-17199-0 · Cited by 321 · see citing works
Recent advances in transition-metal dichalcogenide based nanomaterials for water splitting
Wang, F., Shifa, T. A., Zhan, X., Huang, Y. H., Liu, K., Cheng, Z., Jiang, C., & He, J. (2015) · Nanoscale · doi:10.1039/c5nr06718a · Cited by 410 · see citing works
Ting, L., Deng, Y., Ma, L.-Y., Zhang, Y.-J., Peterson, A., & Yeo, B. S. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02369 · Cited by 304 · see citing works
Copper molybdenum sulfide: a new efficient electrocatalyst for hydrogen production from water
Tran, P. D., Nguyen, M., Pramana, S., Bhattacharjee, A., Chiam, S. Y., Fize, J., Field, M., Artero, V., Wong, L., Loo, J., et al. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22611a · Cited by 298 · see citing works
Li, C., Cao, Q., Wang, F., Xiao, Y., Li, Y., Delaunay, J., & Zhu, H. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00067k · Cited by 490 · see citing works
Kuang, P.-Y., Tong, T., Fan, K., & Yu, J.-G. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b02225 · Cited by 295 · see citing works
Ultrathin S-doped MoSe 2 nanosheets for efficient hydrogen evolution
Xu, C. G., Peng, S., Tan, C., Ang, E. H., Tan, H., Zhang, H., & Yan, Q. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta00458b · Cited by 366 · see citing works
Growth and Activation of an Amorphous Molybdenum Sulfide Hydrogen Evolving Catalyst
Vrubel, H., & Hu, X. (2013) · ACS Catalysis · doi:10.1021/cs400441u · Cited by 292 · see citing works
Self-citationHydrothermal synthesis of MoS2 nanoflowers as highly efficient hydrogen evolution reaction catalysts
Wang, D.-Z., Pan, Z., Wu, Z.-Z., Wang, Z., & Liu, Z.-H. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.04.066 · Cited by 291 · see citing works
- Authors
- Merki, D., Vrubel, H., Rovelli, L., Fierro, S., & Hu, X.
- Affiliations
- École Polytechnique Fédérale de Lausanne (CH)
- Corresponding author
- Hu, Xile
- ORCID
- Hu, Xile
- Venue
- Chemical Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 3
- Issue
- 8
- Pages
- 2515
- ISSN
- 2041-6520 (ISSN-L)
- 2041-6539
- OpenAlex
- W2120703005
- Cited by
- 941
- References
- 0
- Citations by year
- 2026: 17 · 2025: 30 · 2024: 34 · 2023: 53 · 2022: 49 · 2021: 54 · 2020: 78 · 2019: 94 · 2018: 102 · 2017: 115 · 2016: 104 · 2015: 91 · 2014: 74 · 2013: 34 · 2012: 11
- FWCI
- 25.75
- Type
- journal article
- Language
- en
- Open access
- green
- infoscience.epfl.ch
- Locations
- Chemical Science (publishedVersion)
- Infoscience (Ecole Polytechnique Fédérale de Lausanne) (submittedVersion)
- Infoscience (Ecole Polytechnique Fédérale de Lausanne) (submittedVersion, cc-by-nc-nd)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Engineering › Mechanical Engineering › Catalysis and Hydrodesulfurization Studies
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Metalloenzymes and iron-sulfur proteins
- Keywords
- amorphous molybdenum sulfide, hydrogen evolution reaction, non-noble metal catalysts, transition metal doping, ternary sulfides, film growth, surface area, exchange current density, pH dependence
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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