The DOI matches its Crossref record; 20 of the 20 references it cites were found in a registry or an index.
Ultrathin Co3S4 Nanosheets that Synergistically Engineer Spin States and Exposed Polyhedra that Promote Water Oxidation under Neutral Conditions
Abstract
Development of efficient and affordable electrocatalysts in neutral solutions is paramount importance for the renewable energy. Herein, we report that the oxygen evolution reaction (OER) performance of Co 3 S 4 under neutral conditions can be enhanced by exposed octahedral planes and self‐adapted spin states in atomically thin nanosheets. A HAADF image clearly confirmed that the active octahedra with Jahn–Teller distortions were exposed exclusively. Most importantly, in the atomically thin nanosheets, the spin states of Co 3+ in the octahedral self‐adapt from low‐spin to high‐spin states. As a result, the synergistic effect endow the Co 3 S 4 nanosheets with superior OER performance, with exceptional low onset overpotentials of circa 0.31 V in neutral solutions, which is state‐of‐the‐art among inorganic non‐noble metal compounds.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles
Suntivich, J., May, K. J., Gasteiger, H. A., Goodenough, J. B., & Shao-Horn, Y. (2011) · Science · doi:10.1126/science.1212858 · Cited by 5,441
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co 2+
Kanan, M. W., & Nocera, D. G. (2008) · Science · doi:10.1126/science.1162018 · Cited by 4,122
Enhanced catalytic activity in strained chemically exfoliated WS2 nanosheets for hydrogen evolution
Voiry, D., Yamaguchi, H., Li, J., Silva, R., Alves, D. C. B., Fujita, T., Chen, M., Asefa, T., Shenoy, V. B., Eda, G., et al. (2013) · Nature Materials · doi:10.1038/nmat3700 · Cited by 2,641
Xie, J., Zhang, J., Li, S., Grote, F., Zhang, X., Zhang, H., Wang, R., Lei, Y., Pan, B., & Xie, Y. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408329q · Cited by 2,350
Self-citationCatalytic Aluminas: Surface Models and Characterization of Surface Sites
Knözinger, H., & Ratnasamy, P. (1978) · Catalysis Reviews · doi:10.1080/03602457808080878 · Cited by 1,861
Double perovskites as a family of highly active catalysts for oxygen evolution in alkaline solution
Grimaud, A., May, K. J., Carlton, C. E., Lee, Y.-L., Risch, M., Hong, W. T., Zhou, J., & Shao-Horn, Y. (2013) · Nature Communications · doi:10.1038/ncomms3439 · Cited by 1,629
Bao, J., Zhang, X., Fan, B., Zhang, J., Zhou, M., Yang, W., Hu, X., Wang, H., Pan, B., & Xie, Y. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201502226 · Cited by 1,428
Self-citationCheng, F., Shen, J., Peng, B., Pan, Y., Tao, Z., & Chen, J. (2011) · Nature Chemistry · doi:10.1038/nchem.931 · Cited by 1,298
Low Overpotential in Vacancy-Rich Ultrathin CoSe2 Nanosheets for Water Oxidation
Liu, Y., Cheng, H., Lyu, M., Fan, S., Liu, Q., Zhang, W., Zhi, Y., Wang, C., Xiao, C., Wei, S., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5085157 · Cited by 1,094
Self-citationMeng, Y., Song, W., Huang, H., Ren, Z., Chen, S.-Y., & Suib, S. L. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505186m · Cited by 1,083
Research works printed but not linked: 5
- 10.1038/nchem.496 · doi:10.1038/nchem.496
- 10.1038/095561a0 · doi:10.1038/095561a0
- 10.1006/jcat.1994.1140 · doi:10.1006/jcat.1994.1140
- 10.1126/science.1198315 · doi:10.1126/science.1198315
- Li X., 2013, Nat. Mater., 12, 586
Cited by
Nanoarchitectonics for Transition‐Metal‐Sulfide‐Based Electrocatalysts for Water Splitting
Guo, Y., Park, T., Yi, J. W., Henzie, J., Kim, J., Wang, Z., Jiang, B., Bando, Y., Sugahara, Y., Tang, J., et al. (2019) · Advanced Materials · doi:10.1002/adma.201807134 · Cited by 1,402
Li, H., Chen, S., Zhang, Y., Zhang, Q., Jia, X., Zhang, Q., Gu, L., Sun, X., Song, L., & Wang, X. (2018) · Nature Communications · doi:10.1038/s41467-018-04888-0 · Cited by 613
High‐Entropy Metal Sulfide Nanoparticles Promise High‐Performance Oxygen Evolution Reaction
Cui, M., Yang, C., Li, B., Dong, Q., Wu, M., Hwang, S., Xie, H., Wang, X., Wang, G., & Hu, L. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202002887 · Cited by 523
Liu, T., Xie, L., Yang, J., Kong, R., Du, G., Asiri, A. M., Sun, X., & Chen, L. (2017) · ChemElectroChem · doi:10.1002/celc.201700392 · Cited by 390
Jin, Y., Huang, S., Yue, X., Du, H., & Shen, P. K. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b04226 · Cited by 359
Metadata
- Authors
- Liu, Y., Xiao, C., Lyu, M., Lin, Y., Cai, W., Huang, P., Tong, W., Zou, Y., & Xie, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-07-31
- Volume
- 54
- Issue
- 38
- Pages
- 11231-11235
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2105941966
- Cited by
- 355
- References
- 20
- FWCI
- 10.85
- Type
- journal article
- Language
- en
- Open access
- closed
- Funders
- National Basic Research Program of China (2015CB932302)
- National Natural Science Foundation of China (21401182, 21331005, 11321503, 91422303)
- China Postdoctoral Science Foundation (2014M550347)
- Key Laboratory of Neutron Physics (CAEP 2014DB02)
- Fundamental Research Funds for the Central University (WK2340000063, WK 2060190027)
- Opening Project of the Jiangsu Key Laboratory for Environment Functional Materials (SJHG1301)
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Ultrathin Co3S4 Nanosheets that Synergistically Engineer Spin States and Exposed Polyhedra that Promote Water Oxidation under Neutral Conditions. https://app.cochat.ai/papers/10.1002/anie.201505320
- The paper
- Liu, Y., Xiao, C., Lyu, M., Lin, Y., Cai, W., Huang, P., Tong, W., Zou, Y., & Xie, Y. (2015). Ultrathin Co3S4 Nanosheets that Synergistically Engineer Spin States and Exposed Polyhedra that Promote Water Oxidation under Neutral Conditions. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201505320
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
