The DOI matches its Crossref record; 49 of the 49 references it cites were found in a registry or an index.
High‐Entropy Metal Sulfide Nanoparticles Promise High‐Performance Oxygen Evolution Reaction
Open accessAbstract
Transition metal sulfides with a multi‐elemental nature represent a class of promising catalysts for oxygen evolution reaction (OER) owing to their good catalytic activity. However, their synthesis remains a challenge due to the thermodynamic immiscibility of the constituent multimetallic elements in a sulfide structure. Herein, for the first time the synthesis of high‐entropy metal sulfide (HEMS, i.e., (CrMnFeCoNi)Sx) solid solution nanoparticles is reported. Computational and X‐ray photoelectron spectroscopy analysis suggest that the (CrMnFeCoNi)Sx exhibits a synergistic effect among metal atoms that leads to desired electronic states to enhance OER activity. The (CrMnFeCoNi)Sx nanoparticles show one of the best activities (low overpotential 295 mV at 100 mA cm−2 in 1 m KOH solution) and good durability (only slight polarization after 10 h by chronopotentiometry) compared with their unary, binary, ternary, and quaternary sulfide counterparts. This work opens up a new synthesis paradigm for high‐entropy compound nanoparticles for highly efficient electrocatalysis applications.
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Cited by
High-entropy nanoparticles: Synthesis-structure-property relationships and data-driven discovery
Yao, Y., Dong, Q., Brozena, A., Luo, J., Miao, J., Chi, M., Wang, C., Kevrekidis, I. G., Ren, Z. J., Greeley, J., et al. (2022) · Science · doi:10.1126/science.abn3103 · Cited by 1,081
Self-citationHigh-entropy materials for catalysis: A new frontier
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Subnanometer high-entropy alloy nanowires enable remarkable hydrogen oxidation catalysis
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High‐Entropy Nanomaterials for Advanced Electrocatalysis
Lee, S. A., Bu, J., Lee, J., & Jang, H. W. (2023) · Small Science · doi:10.1002/smsc.202200109 · Cited by 95
Metadata
- Authors
- Cui, M., Yang, C., Li, B., Dong, Q., Wu, M., Hwang, S., Xie, H., Wang, X., Wang, G., & Hu, L.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2020-11-30
- Volume
- 11
- Issue
- 3
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W3108348094
- Cited by
- 523
- References
- 49
- FWCI
- 11.18
- Type
- journal article
- Language
- en
- Open access
- green
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- Cui, M., Yang, C., Li, B., Dong, Q., Wu, M., Hwang, S., Xie, H., Wang, X., Wang, G., & Hu, L. (2021). High‐Entropy Metal Sulfide Nanoparticles Promise High‐Performance Oxygen Evolution Reaction. Advanced Energy Materials. https://doi.org/10.1002/aenm.202002887
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