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Cited by 1,109

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Metal–Organic Framework (MOF) Compounds: Photocatalysts for Redox Reactions and Solar Fuel Production

Dhakshinamoorthy, Amarajothi, Asiri, Abdullah M., García, Hermenegildo·2016·Angewandte Chemie International Edition

Abstract

Metal–organic frameworks (MOFs) are crystalline porous materials formed from bi‐ or multipodal organic linkers and transition‐metal nodes. Some MOFs have high structural stability, combined with large flexibility in design and post‐synthetic modification. MOFs can be photoresponsive through light absorption by the organic linker or the metal oxide nodes. Photoexcitation of the light absorbing units in MOFs often generates a ligand‐to‐metal charge‐separation state that can result in photocatalytic activity. In this Review we discuss the advantages and uniqueness that MOFs offer in photocatalysis. We present the best practices to determine photocatalytic activity in MOFs and for the deposition of co‐catalysts. In particular we give examples showing the photocatalytic activity of MOFs in H 2 evolution, CO 2 reduction, photooxygenation, and photoreduction.

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Metadata

Authors
Dhakshinamoorthy, A., Asiri, A. M., & García, H.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2016-03-11
Volume
55
Issue
18
Pages
5414-5445
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2295840750
Cited by
1,109
References
6
FWCI
47.93
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Metal–Organic Framework (MOF) Compounds: Photocatalysts for Redox Reactions and Solar Fuel Production. https://app.cochat.ai/papers/10.1002/anie.201505581
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Dhakshinamoorthy, A., Asiri, A. M., & García, H. (2016). Metal–Organic Framework (MOF) Compounds: Photocatalysts for Redox Reactions and Solar Fuel Production. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201505581

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