The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Reduction of Carbon Dioxide to Formate at Low Overpotential Using a Superbase Ionic Liquid
Open accessAbstract
A new low‐energy pathway is reported for the electrochemical reduction of CO 2 to formate and syngas at low overpotentials, utilizing a reactive ionic liquid as the solvent. The superbasic tetraalkyl phosphonium ionic liquid [P 66614][124Triz] is able to chemisorb CO 2 through equimolar binding of CO 2 with the 1,2,4‐triazole anion. This chemisorbed CO 2 can be reduced at silver electrodes at overpotentials as low as 0.17 V, forming formate. In contrast, physically absorbed CO 2 within the same ionic liquid or in ionic liquids where chemisorption is impossible (such as [P 66614][NTf 2]) undergoes reduction at significantly increased overpotentials, producing only CO as the product.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
Rosen, B. A., Salehi-Khojin, A., Thorson, M. R., Zhu, W., Whipple, D. T., Kenis, P. J. A., & Masel, R. I. (2011) · Science · doi:10.1126/science.1209786 · Cited by 1,558
Switching the Reaction Course of Electrochemical CO 2 Reduction with Ionic Liquids
Sun, L., Ramesha, G. K., Kamat, P. V., & Brennecke, J. F. (2014) · Langmuir · doi:10.1021/la5009076 · Cited by 279
Cited by
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Wagner, A., Sahm, C. D., & Reisner, E. (2020) · Nature Catalysis · doi:10.1038/s41929-020-00512-x · Cited by 731
Zhang, S., Zhang, J., Zhang, Y., & Deng, Y. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00509 · Cited by 659
Li, F., Chen, L., Knowles, G. P., MacFarlane, D. R., & Zhang, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201608279 · Cited by 631
Sulfur-Modulated Tin Sites Enable Highly Selective Electrochemical Reduction of CO2 to Formate
Zheng, X., De Luna, P., García de Arquer, F. P., Zhang, B., Becknell, N., Ross, M. B., Li, Y., Banis, M. N., Li, Y., Liu, M., et al. (2017) · Joule · doi:10.1016/j.joule.2017.09.014 · Cited by 515
Metadata
- Authors
- Hollingsworth, N., Taylor, S. F. R., Galante, M. T., Jacquemin, J., Longo, C., Holt, K. B., de Leeuw, N. H., & Hardacre, C.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-09-25
- Volume
- 54
- Issue
- 47
- Pages
- 14164-14168
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2119816877
- Cited by
- 168
- References
- 2
- FWCI
- 5.96
- Type
- journal article
- Language
- en
- Open access
- bronze
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Reduction of Carbon Dioxide to Formate at Low Overpotential Using a Superbase Ionic Liquid. https://app.cochat.ai/papers/10.1002/anie.201507629
- The paper
- Hollingsworth, N., Taylor, S. F. R., Galante, M. T., Jacquemin, J., Longo, C., Holt, K. B., de Leeuw, N. H., & Hardacre, C. (2015). Reduction of Carbon Dioxide to Formate at Low Overpotential Using a Superbase Ionic Liquid. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201507629
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
