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Triarylboron‐Based Fluorescent Organic Light‐Emitting Diodes with External Quantum Efficiencies Exceeding 20 %

Suzuki, Katsuaki, Kubo, Shosei, Shizu, Katsuyuki, Fukushima, Tatsuya, Wakamiya, Atsushi, Murata, Yasujiro, Adachi, Chihaya, Kaji, Hironori·2015·Angewandte Chemie International Edition

Abstract

Triarylboron compounds have attracted much attention, and found wide use as functional materials because of their electron‐accepting properties arising from the vacant p orbitals on the boron atoms. In this study, we design and synthesize new donor–acceptor triarylboron emitters that show thermally activated delayed fluorescence. These emitters display sky‐blue to green emission and high photoluminescence quantum yields of 87–100 % in host matrices. Organic light‐emitting diodes using these emitting molecules as dopants exhibit high external quantum efficiencies of 14.0–22.8 %, which originate from efficient up‐conversion from triplet to singlet states and subsequent efficient radiative decay from singlet to ground states.

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Metadata

Authors
Suzuki, K., Kubo, S., Shizu, K., Fukushima, T., Wakamiya, A., Murata, Y., Adachi, C., & Kaji, H.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2015-11-13
Volume
54
Issue
50
Pages
15231-15235
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2157139891
Cited by
309
References
0
FWCI
18.60
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Triarylboron‐Based Fluorescent Organic Light‐Emitting Diodes with External Quantum Efficiencies Exceeding 20 %. https://app.cochat.ai/papers/10.1002/anie.201508270
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Suzuki, K., Kubo, S., Shizu, K., Fukushima, T., Wakamiya, A., Murata, Y., Adachi, C., & Kaji, H. (2015). Triarylboron‐Based Fluorescent Organic Light‐Emitting Diodes with External Quantum Efficiencies Exceeding 20 %. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201508270

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.