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A Semi‐Conductive Copper–Organic Framework with Two Types of Photocatalytic Activity
Abstract
Based on the newly designed ligand 4′‐(3,5‐dicarboxyphenyl)‐4,2′:6′,4′′‐terpyridine (DCTP), a unique semi‐conductive 3D framework {[Cu Ι Cu ΙΙ2(DCTP)2]NO 3⋅1.5 DMF}n (1) with a narrow band gap of 2.1 eV, was obtained and structurally characterized. DFT calculations with van de Waals correction employed to explore the electronic structure of 1, clearly revealed its semi‐conductive behavior. Furthermore, we found that 1 exhibits a superior band alignment with water to produce hydrogen and degrade organic pollutants. Without adding any photosensitizers, 1 displays an efficiently photocatalytic hydrogen production in water based on the photo‐generated electrons under UV/Vis light. 1 also exhibits excellent photo‐degradation of methyl blue under visible‐light owing to the strong oxidization of excited holes. It is the first example of MOFs with doubly photocatalytic activities related to photo‐generated electrons and holes, respectively.
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Citations
Cites
Photocatalytic Water Splitting: Recent Progress and Future Challenges
Maeda, K., & Domen, K. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1007966 · Cited by 2,739
Xiang, Q., Yu, J., & Jaroniec, M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302846n · Cited by 2,360
Metal–organic frameworks as platforms for clean energy
Li, S.-L., & Xu, Q. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40507a · Cited by 970
Cited by
Metal–Organic Framework-Based Catalysts with Single Metal Sites
Wei, Y.-S., Zhang, M., Zou, R., & Xu, Q. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00757 · Cited by 1,233
Metal-Organic Frameworks for Energy Applications
Wang, H., Zhu, Q.-L., Zou, R., & Xu, Q. (2017) · Chem · doi:10.1016/j.chempr.2016.12.002 · Cited by 1,200
Photocatalytic Water Splitting—The Untamed Dream: A Review of Recent Advances
Jafari, T., Moharreri, E., Amin, A., Miao, R., Song, W., & Suib, S. (2016) · Molecules · doi:10.3390/molecules21070900 · Cited by 621
Shi, D., Zheng, R., Sun, M., Cao, X., Sun, C., Cui, C., Liu, C., Zhao, J., & Du, M. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201709869 · Cited by 308
Li, D., Yu, S., & Jiang, H. (2018) · Advanced Materials · doi:10.1002/adma.201707377 · Cited by 308
Metadata
- Authors
- Wu, Z., Wang, C., Zhao, B., Dong, J., Lu, F., Wang, W., Wang, W., Wu, G., Cui, J., & Cheng, P.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-01-06
- Volume
- 55
- Issue
- 16
- Pages
- 4938-4942
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2225047176
- Cited by
- 177
- References
- 3
- FWCI
- 12.50
- Type
- journal article
- Language
- en
- Open access
- closed
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