The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.
Gold‐Catalyzed Highly Selective Photoredox C(sp2)−H Difluoroalkylation and Perfluoroalkylation of Hydrazones
Abstract
The first gold‐catalyzed photoredox C(sp 2)−H difluoroalkylation and perfluoroalkylation of hydrazones with readily available R F−Br reagents is reported. The resulting gem‐difluoromethylated and perfluoroalkylated hydrazones are highly functionalized, versatile molecules. A mild reduction of the coupling products can efficiently produce gem‐difluoromethylated β‐amino phosphonic acids and β‐amino acid derivatives. In mechanistic studies, a difluoroalkyl radical intermediate was detected by an EPR spin‐trapping experiment, indicating that a gold‐catalyzed radical pathway is operating.
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Fluorine in Pharmaceuticals: Looking Beyond Intuition
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Visible light photoredox catalysis: applications in organic synthesis
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Solar Synthesis: Prospects in Visible Light Photocatalysis
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Visible‐Light Photoredox Catalysis
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Cited by
Photoredox-Catalyzed C–H Functionalization Reactions
Holmberg-Douglas, N., & Nicewicz, D. A. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00311 · Cited by 989
The recent achievements of redox-neutral radical C–C cross-coupling enabled by visible-light
Xie, J., Jin, H., & Hashmi, A. S. K. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00339k · Cited by 532
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Metadata
- Authors
- Xie, J., Zhang, T., Chen, F., Mehrkens, N., Rominger, F., Rudolph, M., & Hashmi, A. S. K.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-01-21
- Volume
- 55
- Issue
- 8
- Pages
- 2934-2938
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2299152466
- Cited by
- 293
- References
- 42
- FWCI
- 25.84
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
