The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Zeolitic Imidazolate Framework/Graphene Oxide Hybrid Nanosheets as Seeds for the Growth of Ultrathin Molecular Sieving Membranes
Abstract
A defect‐free zeolitic imidazolate framework‐8 (ZIF‐8)/graphene oxide (GO) membrane with a thickness of 100 nm was prepared using two‐dimensional (2D) ZIF‐8/GO hybrid nanosheets as seeds. Hybrid nanosheets with a suitable amount of ZIF‐8 nanocrystals were essential for producing a uniform seeding layer that facilitates fast crystal intergrowth during membrane formation. Moreover, the seeding layer acts as a barrier between two different synthesis solutions, and self‐limits crystal growth and effectively eliminates defects during the contra‐diffusion process. The resulting ultrathin membranes show excellent molecular sieving gas separation properties, such as with a high CO 2/N 2 selectivity of 7.0. This 2D nano‐hybrid seeding strategy can be readily extended to the fabrication of other defect‐free and ultrathin MOF or zeolite molecular sieving membranes for a wide range of separation applications.
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Citations
Cites
Mechanical Properties of Monolayer Graphene Oxide
Suk, J. W., Piner, R. D., An, J., & Ruoff, R. S. (2010) · ACS Nano · doi:10.1021/nn101781v · Cited by 1,194
Zhong, H., Wang, J., Zhang, Y., Xu, W., Xing, W., Xu, D., Zhang, Y., & Zhang, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201408990 · Cited by 938
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Cited by
CO2 Capture and Separations Using MOFs: Computational and Experimental Studies
Yu, J., Xie, L.-H., Li, J.-R., Ma, Y., Seminario, J. M., & Balbuena, P. B. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00626 · Cited by 1,047
Zhang, H., Hou, J., Hu, Y., Wang, P., Ou, R., Jiang, L., Liu, J. Z., Freeman, B. D., Hill, A. J., & Wang, H. (2018) · Science Advances · doi:10.1126/sciadv.aaq0066 · Cited by 593
Self-citationAdvances in metal–organic framework-based membranes
Cheng, Y., Datta, S. J., Zhou, S., Jia, J., Shekhah, O., & Eddaoudi, M. (2022) · Chemical Society Reviews · doi:10.1039/d2cs00031h · Cited by 423
Microporous framework membranes for precise molecule/ion separations
Dou, H., Xu, M., Wang, B., Zhang, Z., Wen, G., Zheng, Y., Luo, D., Zhao, L., Yu, A., Zhang, L., et al. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00552e · Cited by 371
Zhou, S., Wei, Y., Li, L., Duan, Y., Hou, Q., Zhang, L., Ding, L.-X., Xue, J., Wang, H., & Caro, J. (2018) · Science Advances · doi:10.1126/sciadv.aau1393 · Cited by 361
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Metadata
- Authors
- Hu, Y., Wei, J., Liang, Y., Zhang, H., Zhang, X., Shen, W., & Wang, H.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-12-28
- Volume
- 55
- Issue
- 6
- Pages
- 2048-2052
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2203551586
- Cited by
- 337
- References
- 2
- FWCI
- 35.63
- Type
- journal article
- Language
- en
- Open access
- closed
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