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Enhanced Photoexcited Carrier Separation in Oxygen‐Doped ZnIn2S4 Nanosheets for Hydrogen Evolution

Yang, Wenlong, Zhang, Lei, Xie, Junfeng, Zhang, Xiaodong, Liu, Qinghua, Yao, Tao, Wei, Shiqiang, Zhang, Qun, Xie, Yi·2016·Angewandte Chemie International Edition

Abstract

Limited by the relatively sluggish charge‐carrier separation in semiconductors, the photocatalytic performance is still far below what is expected. Herein, a model of ZnIn 2 S 4 (ZIS) nanosheets with oxygen doping is put forward to obtain in‐depth understanding of the role that doping atoms play in photocatalysis. It shows enhanced photocatalytic activity compared with pristine ZIS. The electron dynamics analyzed by ultrafast transient absorption spectroscopy reveals that the average recovery lifetime of photoexcited electrons is increased by 1.53 times upon oxygen incorporation into the ZIS crystals, indicating enhanced separation of photoexcited carriers in oxygen‐doped ZIS nanosheets. As expected, the oxygen‐doped ZIS nanosheets show a remarkably improved photocatalytic activity with a hydrogen evolution rate of up to 2120 μmol h−1 g−1 under visible‐light irradiation, which is 4.5 times higher than that of the pristine ZIS nanosheets.

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Metadata

Authors
Yang, W., Zhang, L., Xie, J., Zhang, X., Liu, Q., Yao, T., Wei, S., Zhang, Q., & Xie, Y.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2016-04-21
Volume
55
Issue
23
Pages
6716-6720
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2339271760
Cited by
613
References
4
FWCI
11.53
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Enhanced Photoexcited Carrier Separation in Oxygen‐Doped ZnIn2S4 Nanosheets for Hydrogen Evolution. https://app.cochat.ai/papers/10.1002/anie.201602543
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Yang, W., Zhang, L., Xie, J., Zhang, X., Liu, Q., Yao, T., Wei, S., Zhang, Q., & Xie, Y. (2016). Enhanced Photoexcited Carrier Separation in Oxygen‐Doped ZnIn2S4 Nanosheets for Hydrogen Evolution. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201602543

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