The DOI matches its Crossref record; 21 of the 21 references it cites were found in a registry or an index.
Triiodide‐Mediated δ‐Amination of Secondary C−H Bonds
Open accessAbstract
The C δ−H amination of unactivated, secondary C−H bonds to form a broad range of functionalized pyrrolidines has been developed by a triiodide (I 3−)‐mediated strategy. By in situ 1) oxidation of sodium iodide and 2) sequestration of the transiently generated iodine (I 2) as I 3−, this approach precludes undesired I 2‐mediated decomposition which can otherwise limit synthetic utility to only weak C(sp 3)−H bonds. The mechanism of this triiodide‐mediated cyclization of unbiased, secondary C(sp 3)−H bonds, by either thermal or photolytic initiation, is supported by NMR and UV/Vis data, as well as intercepted intermediates.
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Cites
Vitaku, E., Smith, D. T., & Njardarson, J. T. (2014) · Journal of Medicinal Chemistry · doi:10.1021/jm501100b · Cited by 6,418
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
Lyons, T. W., & Sanford, M. S. (2010) · Chemical Reviews · doi:10.1021/cr900184e · Cited by 6,119
Palladium(II)‐Catalyzed CH Activation/CC Cross‐Coupling Reactions: Versatility and Practicality
Chen, X., Engle, K. M., Wang, D., & Yu, J. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200806273 · Cited by 4,121
Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation
Colby, D. A., Bergman, R. G., & Ellman, J. A. (2010) · Chemical Reviews · doi:10.1021/cr900005n · Cited by 3,682
CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals
Yamaguchi, J., Yamaguchi, A. D., & Itami, K. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201201666 · Cited by 2,987
Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
Davies, H. M. L., & Manning, J. R. (2008) · Nature · doi:10.1038/nature06485 · Cited by 2,303
Bergman, R. G. (2007) · Nature · doi:10.1038/446391a · Cited by 1,470
C–H functionalization logic in total synthesis
Gutekunst, W. R., & Baran, P. S. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00182a · Cited by 1,399
Miller, A. P. (1941) · American Journal of Public Health and the Nations Health · doi:10.2105/ajph.31.12.1324-a · Cited by 1,381
Site-selective arene C-H amination via photoredox catalysis
Romero, N. A., Margrey, K. A., Tay, N. E., & Nicewicz, D. A. (2015) · Science · doi:10.1126/science.aac9895 · Cited by 930
Cited by
Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Guo, W., Wang, Q., & Zhu, J. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00774a · Cited by 423
Hu, A., Guo, J.-J., Pan, H., Tang, H., Gao, Z., & Zuo, Z. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b13131 · Cited by 384
Metadata
- Authors
- Wappes, E. A., Fosu, S. C., Chopko, T. C., & Nagib, D. A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-07-07
- Volume
- 55
- Issue
- 34
- Pages
- 9974-9978
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2472650499
- Cited by
- 265
- References
- 21
- FWCI
- 18.12
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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