The DOI matches its Crossref record; 28 of the 28 references it cites were found in a registry or an index.
δ-Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer
Abstract
We demonstrate the application of ligand-to-metal charge transfer (LMCT) excitation to the direct catalytic generation of energetically challenging alkoxy radicals from alcohols through a coordination-LMCT-homolysis process with an abundant and inexpensive cerium salt as the catalyst. This catalytic manifold provides a simple and efficient way to utilize the characteristic reactivity and selectivity of transient alkoxy radicals for δ-selective C-H bond functionalization. Under mild redox-neutral conditions without the need for prefunctionalization, this method provides a versatile platform to access molecular complexity from simple and abundant alcohols.
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Cites
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Merging photoredox with nickel catalysis: Coupling of α-carboxyl sp 3 -carbons with aryl halides
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Self-citationRecent progress in the generation and use of nitrogen-centred radicals
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Synthetic Applications of Proton-Coupled Electron Transfer
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Asymmetric copper-catalyzed C-N cross-couplings induced by visible light
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Direct C(sp3)–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals
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O–H hydrogen bonding promotes H-atom transfer from α C–H bonds for C-alkylation of alcohols
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Cited by
Speckmeier, E., Fischer, T. G., & Zeitler, K. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b08933 · Cited by 771
Photocatalytic Late-Stage C–H Functionalization
Bellotti, P., Huang, H.-M., Faber, T., & Glorius, F. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00478 · Cited by 623
Solar-Energy-Mediated Methane Conversion
Song, H., Meng, X., Wang, Z.-J., Liu, H., & Ye, J. (2019) · Joule · doi:10.1016/j.joule.2019.06.023 · Cited by 478
Guo, W., Wang, Q., & Zhu, J. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00774a · Cited by 423
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Metadata
- Authors
- Hu, A., Guo, J.-J., Pan, H., Tang, H., Gao, Z., & Zuo, Z.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-01-30
- Volume
- 140
- Issue
- 5
- Pages
- 1612-1616
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2785830129
- Cited by
- 384
- References
- 28
- FWCI
- 17.69
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hu, A., Guo, J.-J., Pan, H., Tang, H., Gao, Z., & Zuo, Z. (2018). δ-Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b13131
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