The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Ground‐State Chemical Reactivity under Vibrational Coupling to the Vacuum Electromagnetic Field
Open accessAbstract
The ground‐state deprotection of a simple alkynylsilane is studied under vibrational strong coupling to the zero‐point fluctuations, or vacuum electromagnetic field, of a resonant IR microfluidic cavity. The reaction rate decreased by a factor of up to 5.5 when the Si−C vibrational stretching modes of the reactant were strongly coupled. The relative change in the reaction rate under strong coupling depends on the Rabi splitting energy. Product analysis by GC‐MS confirmed the kinetic results. Temperature dependence shows that the activation enthalpy and entropy change significantly, suggesting that the transition state is modified from an associative to a dissociative type. These findings show that vibrational strong coupling provides a powerful approach for modifying and controlling chemical landscapes and for understanding reaction mechanisms.
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Citations
Cites
Room-Temperature Polariton Lasing in an Organic Single-Crystal Microcavity
Kéna-Cohen, S., & Forrest, S. R. (2010) · Nature Photonics · doi:10.1038/nphoton.2010.86 · Cited by 942
Cited by
Tilting a ground-state reactivity landscape by vibrational strong coupling
Thomas, A., Lethuillier-Karl, L., Nagarajan, K., Vergauwe, R. M. A., George, J., Chervy, T., Shalabney, A., Devaux, E., Genet, C., Moran, J., et al. (2019) · Science · doi:10.1126/science.aau7742 · Cited by 852
Self-citationFlick, J., Ruggenthaler, M., Appel, H., & Rubio, A. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1615509114 · Cited by 573
Theoretical Advances in Polariton Chemistry and Molecular Cavity Quantum Electrodynamics
Mandal, A., Taylor, M. A. D., Weight, B. M., Koessler, E. R., Li, X., & Huo, P. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00855 · Cited by 270
Metadata
- Authors
- Thomas, A., George, J., Shalabney, A., Dryzhakov, M., Varma, S. J., Moran, J., Chervy, T., Zhong, X., Devaux, E., Genet, C., Hutchison, J. A., & Ebbesen, T. W.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-08-16
- Volume
- 55
- Issue
- 38
- Pages
- 11462-11466
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2516953064
- Cited by
- 548
- References
- 1
- FWCI
- 16.35
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Thomas, A., George, J., Shalabney, A., Dryzhakov, M., Varma, S. J., Moran, J., Chervy, T., Zhong, X., Devaux, E., Genet, C., Hutchison, J. A., & Ebbesen, T. W. (2016). Ground‐State Chemical Reactivity under Vibrational Coupling to the Vacuum Electromagnetic Field. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201605504
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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