The DOI matches its Crossref record; 59 of the 59 references it cites were found in a registry or an index.
Dehydrogenation of Formic Acid at Room Temperature: Boosting Palladium Nanoparticle Efficiency by Coupling with Pyridinic‐Nitrogen‐Doped Carbon
Abstract
The use of formic acid (FA) to produce molecular H 2 is a promising means of efficient energy storage in a fuel‐cell‐based hydrogen economy. To date, there has been a lack of heterogeneous catalyst systems that are sufficiently active, selective, and stable for clean H 2 production by FA decomposition at room temperature. For the first time, we report that flexible pyridinic‐N‐doped carbon hybrids as support materials can significantly boost the efficiency of palladium nanoparticle for H 2 generation; this is due to prominent surface electronic modulation. Under mild conditions, the optimized engineered Pd/CN 0.25 catalyst exhibited high performance in both FA dehydrogenation (achieving almost full conversion, and a turnover frequency of 5530 h−1 at 25 °C) and the reversible process of CO 2 hydrogenation into FA. This system can lead to a full carbon‐neutral energy cycle.
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Cited by
Metal-Nanoparticle-Catalyzed Hydrogen Generation from Formic Acid
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Metadata
- Authors
- Bi, Q., Lin, J., Liu, Y., He, H., Huang, F., & Cao, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-08-23
- Volume
- 55
- Issue
- 39
- Pages
- 11849-11853
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2508812891
- Cited by
- 357
- References
- 59
- FWCI
- 17.90
- Type
- journal article
- Language
- en
- Open access
- closed
- Funders
- NSF of China (21273044, 21473035, 91545108, 51502331)
- Science & Technology Commission of Shanghai Municipality (16ZR1440400)
- State Key Laboratory of Chemical Engineering (SKL-ChE-15C02)
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- Bi, Q., Lin, J., Liu, Y., He, H., Huang, F., & Cao, Y. (2016). Dehydrogenation of Formic Acid at Room Temperature: Boosting Palladium Nanoparticle Efficiency by Coupling with Pyridinic‐Nitrogen‐Doped Carbon. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201605961
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