The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Single Atom (Pd/Pt) Supported on Graphitic Carbon Nitride as an Efficient Photocatalyst for Visible-Light Reduction of Carbon Dioxide
Open accessAbstract
Reducing carbon dioxide to hydrocarbon fuel with solar energy is significant for high-density solar energy storage and carbon balance. In this work, single atoms of palladium and platinum supported on graphitic carbon nitride (g-C3N4), i.e., Pd/g-C3N4 and Pt/g-C3N4, respectively, acting as photocatalysts for CO2 reduction were investigated by density functional theory calculations for the first time. During CO2 reduction, the individual metal atoms function as the active sites, while g-C3N4 provides the source of hydrogen (H*) from the hydrogen evolution reaction. The complete, as-designed photocatalysts exhibit excellent activity in CO2 reduction. HCOOH is the preferred product of CO2 reduction on the Pd/g-C3N4 catalyst with a rate-determining barrier of 0.66 eV, while the Pt/g-C3N4 catalyst prefers to reduce CO2 to CH4 with a rate-determining barrier of 1.16 eV. In addition, deposition of atom catalysts on g-C3N4 significantly enhances the visible-light absorption, rendering them ideal for visible-light reduction of CO2. Our findings open a new avenue of CO2 reduction for renewable energy supply.
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Metadata
- Authors
- Gao, G., Jiao, Y., Waclawik, E. R., & Du, A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-05-05
- Volume
- 138
- Issue
- 19
- Pages
- 6292-6297
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2343203850
- Cited by
- 1,196
- References
- 7
- FWCI
- 32.45
- Type
- journal article
- Language
- en
- Open access
- green
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- Gao, G., Jiao, Y., Waclawik, E. R., & Du, A. (2016). Single Atom (Pd/Pt) Supported on Graphitic Carbon Nitride as an Efficient Photocatalyst for Visible-Light Reduction of Carbon Dioxide. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.6b02692
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