The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Selective and Efficient Removal of Mercury from Aqueous Media with the Highly Flexible Arms of a BioMOF
Open accessAbstract
A robust and water‐stable metal–organic framework (MOF), featuring hexagonal channels decorated with methionine residues (1), selectively captures toxic species such as CH 3 Hg+ and Hg 2+ from water. 1 exhibits the largest Hg 2+ uptake capacity ever reported for a MOF, decreasing the [Hg 2+] and [CH 3 Hg+] concentrations in potable water from highly hazardous 10 ppm to the much safer values of 6 and 27 ppb, respectively. Just like with biological systems, the high‐performance metal capture also involves a molecular recognition process. Both CH 3 Hg+ and Hg 2+ are efficiently immobilized by specific conformations adopted by the flexible thioether “claws” decorating the pores of 1. This leads to very stable structural conformations reminiscent of those responsible for the biological activity of the enzyme mercury reductase (MR).
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BioMOFs: Metal–Organic Frameworks for Biological and Medical Applications
McKinlay, A. C., Morris, R. E., Horcajada, P., Férey, G., Gref, R., Couvreur, P., & Serre, C. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000048 · Cited by 1,256
Subrahmanyam, K. S., Malliakas, C. D., Sarma, D., Armatas, G. S., Wu, J., & Kanatzidis, M. G. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b09110 · Cited by 193
Cited by
Metal–organic frameworks for heavy metal removal from water
Kobielska, P. A., Howarth, A. J., Farha, O. K., & Nayak, S. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.12.010 · Cited by 1,014
Wang, L., Hou, D., Cao, Y., Ok, Y. S., Tack, F. M. G., Rinklebe, J., & O'Connor, D. (2020) · Environment International · doi:10.1016/j.envint.2019.105281 · Cited by 396
π-π stacking interactions: Non-negligible forces for stabilizing porous supramolecular frameworks
Deng, J.-H., Luo, J., Mao, Y.-L., Lai, S., Gong, Y.-N., Zhong, D.-C., & Lu, T.-B. (2020) · Science Advances · doi:10.1126/sciadv.aax9976 · Cited by 380
Incorporation of biomolecules in Metal-Organic Frameworks for advanced applications
An, H., Li, M., Gao, J., Zhang, Z., Ma, S., & Chen, Y. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.01.001 · Cited by 336
Fortea-Pérez, F. R., Mon, M., Ferrando-Soria, J., Boronat, M., Leyva-Pérez, A., Corma, A., Herrera, J. M., Osadchii, D., Gascon, J., Armentano, D., et al. (2017) · Nature Materials · doi:10.1038/nmat4910 · Cited by 287
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Metadata
- Authors
- Mon, M., Lloret, F., Ferrando‐Soria, J., Martí‐Gastaldo, C., Armentano, D., & Pardo, E.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-08-16
- Volume
- 55
- Issue
- 37
- Pages
- 11167-11172
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2514080813
- Cited by
- 191
- References
- 2
- FWCI
- 8.89
- Type
- journal article
- Language
- en
- Open access
- bronze
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