Ion-Exchangeable Molybdenum Sulfide Porous Chalcogel: Gas Adsorption and Capture of Iodine and Mercury
Abstract
We report the synthesis of ion-exchangeable molybdenum sulfide chalcogel through an oxidative coupling process, using (NH4)2MoS4 and iodine. After supercritical drying, the MoS(x) amorphous aerogel shows a large surface area up to 370 m(2)/g with a broad range of pore sizes. X-ray photoelectron spectroscopic and pair distribution function analyses reveal that Mo(6+) species undergo reduction during network assembly to produce Mo(4+)-containing species where the chalcogel network consists of [Mo3S13] building blocks comprising triangular Mo metal clusters and S2(2-) units. The optical band gap of the brown-black chalcogel is ∼1.36 eV. The ammonium sites present in the molybdenum sulfide chalcogel network are ion-exchangeable with K(+) and Cs(+) ions. The molybdenum sulfide aerogel exhibits high adsorption selectivities for CO2 and C2H6 over H2 and CH4. The aerogel also possesses high affinity for iodine and mercury.
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The incorporation of CNT into the MoSx aerogel increased the surface area, although the intrinsic surface area of CNT was smaller (88.9 m2/g).
“The incorporation of CNT into the MoSx aerogel increased the surface area, although the intrinsic surface area of CNT was smaller (88.9 m2/g).”
From Synthesis of amorphous MoSx and MoSx/carbon nanotubes composite aerogels as effective hydrogen evolution reaction catalysts (2018) · cites this paper as [19]
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- Authors
- Subrahmanyam, K. S., Malliakas, C. D., Sarma, D., Armatas, G. S., Wu, J., & Kanatzidis, M. G.
- Affiliations
- Northwestern University (US)
- University of Crete (GR)
- Corresponding author
- Kanatzidis, Mercouri G.
- ORCID
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-10-22
- Volume
- 137
- Issue
- 43
- Pages
- 13943-13948
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2232191890
- Cited by
- 193
- References
- 57
- Citations by year
- 2026: 14 · 2025: 20 · 2024: 25 · 2023: 16 · 2022: 17 · 2021: 18 · 2020: 19 · 2019: 21 · 2018: 14 · 2017: 15 · 2016: 12 · 2015: 1
- FWCI
- 6.23
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the American Chemical Society (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Office of Nuclear Energy
- Indo-US Science and Technology Forum
- Honeywell International Inc.
- Topics
- Physical Sciences › Chemistry › Spectroscopy › Aerogels and thermal insulation
- Physical Sciences › Engineering › Mechanical Engineering › Carbon Dioxide Capture Technologies
- Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
- Keywords
- molybdenum sulfide, porous aerogel, ion exchange, oxidative coupling, iodine adsorption, mercury adsorption, gas separation, CO2 adsorption, optical band gap, supercritical drying
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