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A Dinuclear Cobalt Cryptate as a Homogeneous Photocatalyst for Highly Selective and Efficient Visible‐Light Driven CO2 Reduction to CO in CH3CN/H2O Solution
Abstract
A dinuclear cobalt complex [Co 2(OH)L 1](ClO 4)3 (1, L 1=N[(CH 2)2 NHCH 2(m‐C 6 H 4)CH 2 NH(CH 2)2]3 N) displays high selectivity and efficiency for the photocatalytic reduction of CO 2 to CO in CH 3 CN/H 2 O (v/v=4:1) under a 450 nm LED light irradiation, with a light intensity of 100 mW cm−2. The selectivity reaches as high as 98 %, and the turnover numbers (TON) and turnover frequencies (TOF) reach as high as 16896 and 0.47 s−1, respectively, with the calculated quantum yield of 0.04 %. Such high activity can be attributed to the synergistic catalysis effect between two Co II ions within 1, which is strongly supported by the results of control experiments and DFT calculations.
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Cites
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
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Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes
Dalle, K. E., Warnan, J., Leung, J. J., Reuillard, B., Karmel, I. S., & Reisner, E. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00392 · Cited by 912
Computational Approach to Molecular Catalysis by 3d Transition Metals: Challenges and Opportunities
Vogiatzis, K. D., Polynski, M. V., Kirkland, J. K., Townsend, J., Hashemi, A., Liu, C., & Pidko, E. A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00361 · Cited by 423
Atomic‐Level Reactive Sites for Semiconductor‐Based Photocatalytic CO2 Reduction
Zhang, Y., Xia, B., Ran, J., Davey, K., & Qiao, S. Z. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201903879 · Cited by 423
Boutin, E., Merakeb, L., Ma, B., Boudy, B., Wang, M., Bonin, J., Anxolabéhère-Mallart, E., & Robert, M. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00218f · Cited by 423
Deacy, A. C., Kilpatrick, A. F. R., Regoutz, A., & Williams, C. K. (2020) · Nature Chemistry · doi:10.1038/s41557-020-0450-3 · Cited by 325
Metadata
- Authors
- Ouyang, T., Huang, H., Wang, J., Zhong, D., & Lu, T.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-12-13
- Volume
- 56
- Issue
- 3
- Pages
- 738-743
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2566456487
- Cited by
- 337
- References
- 1
- FWCI
- 7.60
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ouyang, T., Huang, H., Wang, J., Zhong, D., & Lu, T. (2017). A Dinuclear Cobalt Cryptate as a Homogeneous Photocatalyst for Highly Selective and Efficient Visible‐Light Driven CO2 Reduction to CO in CH3CN/H2O Solution. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201610607
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