The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Understanding of Strain Effects in the Electrochemical Reduction of CO2: Using Pd Nanostructures as an Ideal Platform
Abstract
Tuning the surface strain of heterogeneous catalysts represents a powerful strategy to engineer their catalytic properties by altering the electronic structures. However, a clear and systematic understanding of strain effect in electrochemical reduction of carbon dioxide is still lacking, which restricts the use of surface strain as a tool to optimize the performance of electrocatalysts. Herein, we demonstrate the strain effect in electrochemical reduction of CO 2 by using Pd octahedra and icosahedra with similar sizes as a well‐defined platform. The Pd icosahedra/C catalyst shows a maximum Faradaic efficiency for CO production of 91.1 % at −0.8 V versus reversible hydrogen electrode (vs. RHE), 1.7‐fold higher than the maximum Faradaic efficiency of Pd octahedra/C catalyst at −0.7 V (vs. RHE). The combination of molecular dynamic simulations and density functional theory calculations reveals that the tensile strain on the surface of icosahedra boosts the catalytic activity by shifting up the d‐band center and thus strengthening the adsorption of key intermediate COOH*. This strain effect was further verified directly by the surface valence‐band photoemission spectra and electrochemical analysis.
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Cites
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784
Direct Capture of CO2 from Ambient Air
Sanz-Pérez, E. S., Murdock, C. R., Didas, S. A., & Jones, C. W. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00173 · Cited by 2,406
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Kim, D., Resasco, J., Yu, Y., Asiri, A. M., & Yang, P. (2014) · Nature Communications · doi:10.1038/ncomms5948 · Cited by 1,374
Tuning the activity of Pt alloy electrocatalysts by means of the lanthanide contraction
Escudero-Escribano, M., Malacrida, P., Hansen, M. H., Vej-Hansen, U. G., Velázquez-Palenzuela, A., Tripkovic, V., Schiøtz, J., Rossmeisl, J., Stephens, I. E. L., & Chorkendorff, I. (2016) · Science · doi:10.1126/science.aad8892 · Cited by 1,057
Cited by
Enhanced Nitrate-to-Ammonia Activity on Copper–Nickel Alloys via Tuning of Intermediate Adsorption
Wang, Y., Xu, A., Wang, Z., Huang, L., Li, J., Li, F., Wicks, J., Luo, M., Nam, D.-H., Tan, C.-S., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b13347 · Cited by 1,380
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Pan, Y., Lin, R., Chen, Y., Liu, S., Zhu, W., Cao, X., Chen, W., Wu, K., Cheong, W.-C., Wang, Y., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b00814 · Cited by 1,242
CO2 Reduction: From the Electrochemical to Photochemical Approach
Wu, J., Huang, Y., Ye, W., & Li, Y. (2017) · Advanced Science · doi:10.1002/advs.201700194 · Cited by 937
Large-Scale and Highly Selective CO2 Electrocatalytic Reduction on Nickel Single-Atom Catalyst
Zheng, T., Jiang, K., Ta, N., Hu, Y., Zeng, J., Liu, J., & Wang, H. (2019) · Joule · doi:10.1016/j.joule.2018.10.015 · Cited by 887
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Metadata
- Authors
- Huang, H., Jia, H., Liu, Z., Gao, P., Zhao, J., Luo, Z., Yang, J., & Zeng, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-02-20
- Volume
- 56
- Issue
- 13
- Pages
- 3594-3598
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2589457549
- Cited by
- 402
- References
- 5
- FWCI
- 11.95
- Type
- journal article
- Language
- en
- Open access
- closed
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