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Cited by 265

The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.

The Nature of Ion Conduction in Methylammonium Lead Iodide: A Multimethod Approach

Open access
Senocrate, Alessandro, Moudrakovski, Igor, Kim, Gee Yeong, Yang, Tae‐Youl, Gregori, Giuliano, Grätzel, Michael, Maier, Joachim·2017·Angewandte Chemie International Edition

Abstract

By applying a multitude of experimental techniques including 1 H, 14 N, 207 Pb NMR and 127 I NMR/NQR, tracer diffusion, reaction cell and doping experiments, as well as stoichiometric variation, conductivity, and polarization experiments, iodine ions are unambiguously shown to be the mobile species in CH 3 NH 3 PbI 3, with iodine vacancies shown to represent the mechanistic centers under equilibrium conditions. Pb 2+ and CH 3 NH 3+ ions do not significantly contribute to the long range transport (upper limits for their contributions are given), whereby the latter exhibit substantial local motion. The decisive electronic contribution to the mixed conductivity in the experimental window stems from electron holes. As holes can be associated with iodine orbitals, local variations of the iodine stoichiometry may be fast and enable light effects on ion transport.

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Metadata

Authors
Senocrate, A., Moudrakovski, I., Kim, G. Y., Yang, T., Gregori, G., Grätzel, M., & Maier, J.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2017-05-30
Volume
56
Issue
27
Pages
7755-7759
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2617165101
Cited by
265
References
40
FWCI
14.77
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: The Nature of Ion Conduction in Methylammonium Lead Iodide: A Multimethod Approach. https://app.cochat.ai/papers/10.1002/anie.201701724
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Senocrate, A., Moudrakovski, I., Kim, G. Y., Yang, T., Gregori, G., Grätzel, M., & Maier, J. (2017). The Nature of Ion Conduction in Methylammonium Lead Iodide: A Multimethod Approach. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201701724

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