The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.
The Nature of Ion Conduction in Methylammonium Lead Iodide: A Multimethod Approach
Open accessAbstract
By applying a multitude of experimental techniques including 1 H, 14 N, 207 Pb NMR and 127 I NMR/NQR, tracer diffusion, reaction cell and doping experiments, as well as stoichiometric variation, conductivity, and polarization experiments, iodine ions are unambiguously shown to be the mobile species in CH 3 NH 3 PbI 3, with iodine vacancies shown to represent the mechanistic centers under equilibrium conditions. Pb 2+ and CH 3 NH 3+ ions do not significantly contribute to the long range transport (upper limits for their contributions are given), whereby the latter exhibit substantial local motion. The decisive electronic contribution to the mixed conductivity in the experimental window stems from electron holes. As holes can be associated with iodine orbitals, local variations of the iodine stoichiometry may be fast and enable light effects on ion transport.
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Cites
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
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Self-citationIonic transport in hybrid lead iodide perovskite solar cells
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Self-citationOrganometal halide perovskite solar cells: degradation and stability
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Cited by
Metal halide perovskites for light-emitting diodes
Liu, X.-K., Xu, W., Bai, S., Jin, Y., Wang, J., Friend, R. H., & Gao, F. (2021) · Nature Materials · doi:10.1038/s41563-020-0784-7 · Cited by 1,515
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Self-citationImproving the Stability of Metal Halide Perovskite Materials and Light‐Emitting Diodes
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Futscher, M. H., Lee, J. M., McGovern, L., Muscarella, L. A., Wang, T., Haider, M. I., Fakharuddin, A., Schmidt-Mende, L., & Ehrler, B. (2019) · Materials Horizons · doi:10.1039/c9mh00445a · Cited by 409
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Metadata
- Authors
- Senocrate, A., Moudrakovski, I., Kim, G. Y., Yang, T., Gregori, G., Grätzel, M., & Maier, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-05-30
- Volume
- 56
- Issue
- 27
- Pages
- 7755-7759
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2617165101
- Cited by
- 265
- References
- 40
- FWCI
- 14.77
- Type
- journal article
- Language
- en
- Open access
- hybrid
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