The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Surface Modification of Two‐Dimensional Metal–Organic Layers Creates Biomimetic Catalytic Microenvironments for Selective Oxidation
Abstract
Microenvironments in enzymes play crucial roles in controlling the activities and selectivities of reaction centers. Herein we report the tuning of the catalytic microenvironments of metal–organic layers (MOLs), a two‐dimensional version of metal–organic frameworks (MOFs) with thickness down to a monolayer, to control product selectivities. By modifying the secondary building units (SBUs) of MOLs with monocarboxylic acids, such as gluconic acid, we changed the hydrophobicity/hydrophilicity around the active sites and fine‐tuned the selectivity in photocatalytic oxidation of tetrahydrofuran (THF) to exclusively afford butyrolactone (BTL), likely a result of prolonging the residence time of reaction intermediates in the hydrophilic microenvironment of catalytic centers. Our work highlights new opportunities in using functional MOLs as highly tunable and selective two‐dimensional catalytic materials.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Cited by
Metal–Organic Frameworks as Platforms for Catalytic Applications
Jiao, L., Wang, Y., Jiang, H., & Xu, Q. (2018) · Advanced Materials · doi:10.1002/adma.201703663 · Cited by 1,717
Two-dimensional metal–organic framework nanosheets: synthesis and applications
Zhao, M., Huang, Y., Peng, Y., Huang, Z., Ma, Q., & Zhang, H. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00268a · Cited by 1,348
Self-citationMetal–Organic Framework-Based Catalysts with Single Metal Sites
Wei, Y.-S., Zhang, M., Zou, R., & Xu, Q. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00757 · Cited by 1,233
Chakraborty, G., Park, I.-H., Medishetty, R., & Vittal, J. J. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01049 · Cited by 928
Li, G., Zhao, S., Zhang, Y., & Tang, Z. (2018) · Advanced Materials · doi:10.1002/adma.201800702 · Cited by 521
Metadata
- Authors
- Shi, W., Cao, L., Zhang, H., Zhou, X., An, B., Lin, Z., Dai, R., Li, J., Wang, C., & Lin, W.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-06-05
- Volume
- 56
- Issue
- 33
- Pages
- 9704-9709
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2618943588
- Cited by
- 187
- References
- 1
- FWCI
- 10.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shi, W., Cao, L., Zhang, H., Zhou, X., An, B., Lin, Z., Dai, R., Li, J., Wang, C., & Lin, W. (2017). Surface Modification of Two‐Dimensional Metal–Organic Layers Creates Biomimetic Catalytic Microenvironments for Selective Oxidation. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201703675
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