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A Rechargeable Li‐CO2 Battery with a Gel Polymer Electrolyte
Abstract
The utilization of CO 2 in Li‐CO 2 batteries is attracting extensive attention. However, the poor rechargeability and low applied current density have remained the Achilles’ heel of this energy device. The gel polymer electrolyte (GPE), which is composed of a polymer matrix filled with tetraglyme‐based liquid electrolyte, was used to fabricate a rechargeable Li‐CO 2 battery with a carbon nanotube‐based gas electrode. The discharge product of Li 2 CO 3 formed in the GPE‐based Li‐CO 2 battery exhibits a particle‐shaped morphology with poor crystallinity, which is different from the contiguous polymer‐like and crystalline discharge product in conventional Li‐CO 2 battery using a liquid electrolyte. Accordingly, the GPE‐based battery shows much improved electrochemical performance. The achieved cycle life (60 cycles) and rate capability (maximum applied current density of 500 mA g−1) are much higher than most of previous reports, which points a new way to develop high‐performance Li‐CO 2 batteries.
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Negative emissions physically needed to keep global warming below 2 °C
Gasser, T., Guivarch, C., Tachiiri, K., Jones, C. D., & Ciais, P. (2015) · Nature Communications · doi:10.1038/ncomms8958 · Cited by 374
Cited by
Recent advances in understanding Li–CO2 electrochemistry
Liu, B., Sun, Y., Liu, L., Chen, J., Yang, B., Xu, S., & Yan, X. (2019) · Energy & Environmental Science · doi:10.1039/c8ee03417f · Cited by 317
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Metadata
- Authors
- Li, C., Guo, Z., Yang, B., Liu, Y., Wang, Y., & Xia, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-06-30
- Volume
- 56
- Issue
- 31
- Pages
- 9126-9130
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2626067675
- Cited by
- 201
- References
- 1
- FWCI
- 8.50
- Type
- journal article
- Language
- en
- Open access
- closed
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- Li, C., Guo, Z., Yang, B., Liu, Y., Wang, Y., & Xia, Y. (2017). A Rechargeable Li‐CO2 Battery with a Gel Polymer Electrolyte. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201705017
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