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Ni3FeN‐Supported Fe3Pt Intermetallic Nanoalloy as a High‐Performance Bifunctional Catalyst for Metal–Air Batteries
Open accessAbstract
Electrocatalysts for both the oxygen reduction and evolution reactions (ORR and OER) are vital for the performances of rechargeable metal–air batteries. Herein, we report an advanced bifunctional oxygen electrocatalyst consisting of porous metallic nickel‐iron nitride (Ni 3 FeN) supporting ordered Fe 3 Pt intermetallic nanoalloy. In this hybrid catalyst, the bimetallic nitride Ni 3 FeN mainly contributes to the high activity for the OER while the ordered Fe 3 Pt nanoalloy contributes to the excellent activity for the ORR. Robust Ni 3 FeN‐supported Fe 3 Pt catalysts show superior catalytic performance to the state‐of‐the‐art ORR catalyst (Pt/C) and OER catalyst (Ir/C). The Fe 3 Pt/Ni 3 FeN bifunctional catalyst enables Zn–air batteries to achieve a long‐term cycling performance of over 480 h at 10 mA cm−2 with high efficiency. The extraordinarily high performance of the Fe 3 Pt/Ni 3 FeN bifunctional catalyst makes it a very promising air cathode in alkaline electrolyte.
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Cites
Electrocatalyst approaches and challenges for automotive fuel cells
Debe, M. K. (2012) · Nature · doi:10.1038/nature11115 · Cited by 5,885
Jia, X., Zhao, Y., Chen, G., Shang, L., Shi, R., Kang, X., Waterhouse, G. I. N., Wu, L., Tung, C., & Zhang, T. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201502585 · Cited by 773
Electrocatalytic Activity of Ordered Intermetallic Phases for Fuel Cell Applications
Casado-Rivera, E., Volpe, D. J., Alden, L., Lind, C., Downie, C., Vázquez-Alvarez, T., Angelo, A. C. D., DiSalvo, F. J., & Abruña, H. D. (2004) · Journal of the American Chemical Society · doi:10.1021/ja038497a · Cited by 521
Wang, Y., Xie, C., Liu, D., Huang, X., Huo, J., & Wang, S. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b05811 · Cited by 315
Cited by
Raveendran, A., Chandran, M., & Dhanusuraman, R. (2023) · RSC Advances · doi:10.1039/d2ra07642j · Cited by 892
Han, X., Ling, X., Wang, Y., Ma, T., Zhong, C., Hu, W., & Deng, Y. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201901109 · Cited by 658
Aqueous metal-air batteries: Fundamentals and applications
Liu, Q., Pan, Z., Wang, E., An, L., & Sun, G. (2020) · Energy Storage Materials · doi:10.1016/j.ensm.2019.12.011 · Cited by 417
Ghosh, S., & Basu, R. N. (2018) · Nanoscale · doi:10.1039/c8nr01032c · Cited by 346
Guo, H., Feng, Q., Zhu, J., Xu, J., Li, Q., Liu, S., Xu, K., Zhang, C., & Liu, T. (2019) · Journal of Materials Chemistry A · doi:10.1039/c8ta11400e · Cited by 306
Metadata
- Authors
- Cui, Z., Fu, G., Li, Y., & Goodenough, J. B.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-07-13
- Volume
- 56
- Issue
- 33
- Pages
- 9901-9905
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2732308955
- Cited by
- 212
- References
- 4
- FWCI
- 7.69
- Type
- journal article
- Language
- en
- Open access
- green
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- Cui, Z., Fu, G., Li, Y., & Goodenough, J. B. (2017). Ni3FeN‐Supported Fe3Pt Intermetallic Nanoalloy as a High‐Performance Bifunctional Catalyst for Metal–Air Batteries. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201705778
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