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Blue‐Emissive Cobalt(III) Complexes and Their Use in the Photocatalytic Trifluoromethylation of Polycyclic Aromatic Hydrocarbons
Open accessAbstract
Room‐temperature luminescent Co III complexes (1 and 2) are presented that exhibit intense ligand‐to‐metal and ligand‐to‐ligand charge transfer absorption in the low‐energy UV region (λabs≈360–400 nm) and low‐negative quasi‐reversible reduction events (E1/2(red)=−0.58 V and −0.39 V vs. SCE for 1 and 2, respectively). The blue emission of 1 and 2 at RT is due to the large bite angles and strong σ‐donation of the ligands, the combined effect of which helps to separate the emissive 3 LMCT (triplet ligand‐to‐metal charge transfer) and the non‐emissive 3 MC (triplet metal‐centered) states. 1 and 2 were found to be powerful photo‐oxidants (E =2.26 V and 2.75 V vs. SCE of 1 and 2, respectively) and were used as inexpensive photoredox catalysts for the regioselective mono(trifluoromethylation) of polycyclic aromatic hydrocarbons (PAHs) in good yields (ca. 40–58 %).
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Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Cited by
Lee, L. C.-C., & Lo, K. K.-W. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c03437 · Cited by 279
A Near‐Infrared‐II Emissive Chromium(III) Complex
Sinha, N., Jiménez, J., Pfund, B., Prescimone, A., Piguet, C., & Wenger, O. S. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202106398 · Cited by 105
Metadata
- Authors
- Pal, A. K., Li, C., Hanan, G. S., & Zysman‐Colman, E.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-06-04
- Volume
- 57
- Issue
- 27
- Pages
- 8027-8031
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2799403769
- Cited by
- 173
- References
- 1
- FWCI
- 5.37
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Pal, A. K., Li, C., Hanan, G. S., & Zysman‐Colman, E. (2018). Blue‐Emissive Cobalt(III) Complexes and Their Use in the Photocatalytic Trifluoromethylation of Polycyclic Aromatic Hydrocarbons. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201802532
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