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Cited by 211

The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.

Iron Porphyrins Embedded into a Supramolecular Porous Organic Cage for Electrochemical CO2 Reduction in Water

Open access
Smith, Peter T., Benke, Bahiru Punja, Cao, Zhi, Kim, Younghoon, Nichols, Eva M., Kim, Kimoon, Chang, Christopher J.·2018·Angewandte Chemie International Edition

Abstract

A porous organic cage composed of six iron tetraphenylporphyrins was used as a supramolecular catalyst for electrochemical CO 2‐to‐CO conversion. This strategy enhances active site exposure and substrate diffusion relative to the monomeric catalyst, resulting in CO generation with near‐quantitative Faradaic efficiency in pH 7.3 water, with activities reaching 55 250 turnovers. These results provide a starting point for the design of supramolecular catalysts that can exploit the properties of the surrounding matrix yet retain the tunability of the original molecular unit.

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Crossref · 10.1002/anie.201803873

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Metadata

Authors
Smith, P. T., Benke, B. P., Cao, Z., Kim, Y., Nichols, E. M., Kim, K., & Chang, C. J.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2018-07-05
Volume
57
Issue
31
Pages
9684-9688
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2809616088
Cited by
211
References
4
FWCI
5.26
Type
journal article
Language
en
Open access
green

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Smith, P. T., Benke, B. P., Cao, Z., Kim, Y., Nichols, E. M., Kim, K., & Chang, C. J. (2018). Iron Porphyrins Embedded into a Supramolecular Porous Organic Cage for Electrochemical CO2 Reduction in Water. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201803873

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