The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Boosting Hydrogen Production by Anodic Oxidation of Primary Amines over a NiSe Nanorod Electrode
Abstract
For electrocatalytic water splitting, the sluggish anodic oxygen evolution reaction (OER) restricts the cathodic hydrogen evolution reaction (HER). Therefore, developing an alternative anodic reaction with accelerating kinetics to produce value‐added chemicals, especially coupled with HER, is of great importance. Now, a thermodynamically more favorable primary amine (−CH 2−NH 2) electrooxidation catalyzed by NiSe nanorod arrays in water is reported to replace OER for enhancing HER. The increased H 2 production can be obtained at cathode; meanwhile, a variety of aromatic and aliphatic primary amines are selectively electrooxidized to nitriles with good yields at the anode. Mechanistic investigations suggest that Ni II/Ni III may serve as the redox active species for the primary amines transformation. Hydrophobic nitrile products can readily escape from aqueous electrolyte/electrode interface, avoiding the deactivation of the catalyst and thus contributing to continuous gram‐scale synthesis.
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Cites
Opportunities and challenges for a sustainable energy future
Chu, S., & Majumdar, A. (2012) · Nature · doi:10.1038/nature11475 · Cited by 12,550
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388
Metallic Nickel Nitride Nanosheets Realizing Enhanced Electrochemical Water Oxidation
Xu, K., Chen, P., Li, X., Tong, Y., Ding, H., Wu, X., Chu, W., Peng, Z., Wu, C., & Xie, Y. (2015) · Journal of the American Chemical Society · doi:10.1021/ja5119495 · Cited by 1,115
Cited by
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Recent Advancements in Electrochemical Hydrogen Production via Hybrid Water Splitting
Qian, Q., Zhu, Y., Ahmad, N., Feng, Y., Zhang, H., Cheng, M., Liu, H., Xiao, C., Zhang, G., & Xie, Y. (2024) · Advanced Materials · doi:10.1002/adma.202306108 · Cited by 399
Trimetallic Spinel NiCo2−xFexO4 Nanoboxes for Highly Efficient Electrocatalytic Oxygen Evolution
Huang, Y., Zhang, S. L., Lu, X. F., Wu, Z., Luan, D., & Lou, X. W. (. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202103058 · Cited by 380
Self-citationActivated Ni–OH Bonds in a Catalyst Facilitates the Nucleophile Oxidation Reaction
Chen, W., Wang, Y., Wu, B., Shi, J., Li, Y., Xu, L., Xie, C., Zhou, W., Huang, Y., Wang, T., et al. (2022) · Advanced Materials · doi:10.1002/adma.202105320 · Cited by 200
Self-citationCircumventing Challenges: Design of Anodic Electrocatalysts for Hybrid Water Electrolysis Systems
Wang, H., Sun, M., Ren, J., & Yuan, Z. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202203568 · Cited by 183
Metadata
- Authors
- Huang, Y., Chong, X., Liu, C., Liang, Y., & Zhang, B.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-09-11
- Volume
- 57
- Issue
- 40
- Pages
- 13163-13166
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2885434353
- Cited by
- 458
- References
- 3
- FWCI
- 8.37
- Type
- journal article
- Language
- en
- Open access
- closed
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