The DOI matches its Crossref record; 28 of the 28 references it cites were found in a registry or an index.
Fluoride‐Free Synthesis of Two‐Dimensional Titanium Carbide (MXene) Using A Binary Aqueous System
Abstract
Two‐dimensional (2D) titanium carbide (Ti 3 C 2) is emerging as an important member of the MXene family. However, fluoride‐based synthetic procedures remain an impediment to the practical applications of this promising class of materials. Here we demonstrate an efficient fluoride‐free etching method based on the anodic corrosion of titanium aluminium carbide (Ti 3 AlC 2) in a binary aqueous electrolyte. The dissolution of aluminium followed by in situ intercalation of ammonium hydroxide results in the extraction of carbide flakes (Ti 3 C 2 Tx, T=O, OH) with sizes up to 18.6 μm and high yield (over 90 %) of mono‐ and bilayers. All‐solid‐state supercapacitor based on exfoliated sheets exhibits high areal and volumetric capacitances of 220 mF cm−2 and 439 F cm−3, respectively, at a scan rate of 10 mV s−1, superior to those of LiF/HCl‐etched MXenes. Our strategy paves a safe way to the scalable synthesis and application of MXene materials.
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Cites
Two‐Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2
Naguib, M., Kurtoglu, M., Presser, V., Lu, J., Niu, J., Heon, M., Hultman, L., Gogotsi, Y., & Barsoum, M. W. (2011) · Advanced Materials · doi:10.1002/adma.201102306 · Cited by 11,855
2D metal carbides and nitrides (MXenes) for energy storage
Anasori, B., Lukatskaya, M. R., & Gogotsi, Y. (2017) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.98 · Cited by 7,440
A simple measure of electron localization in atomic and molecular systems
Becke, A. D., & Edgecombe, K. E. (1990) · The Journal of Chemical Physics · doi:10.1063/1.458517 · Cited by 7,145
25th Anniversary Article: MXenes: A New Family of Two‐Dimensional Materials
Naguib, M., Mochalin, V. N., Barsoum, M. W., & Gogotsi, Y. (2014) · Advanced Materials · doi:10.1002/adma.201304138 · Cited by 6,414
Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance
Ghidiu, M., Lukatskaya, M. R., Zhao, M.-Q., Gogotsi, Y., & Barsoum, M. W. (2014) · Nature · doi:10.1038/nature13970 · Cited by 5,997
Electromagnetic interference shielding with 2D transition metal carbides (MXenes)
Shahzad, F., Alhabeb, M., Hatter, C. B., Anasori, B., Man Hong, S., Koo, C. M., & Gogotsi, Y. (2016) · Science · doi:10.1126/science.aag2421 · Cited by 5,201
Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (Ti3C2Tx MXene)
Alhabeb, M., Maleski, K., Anasori, B., Lelyukh, P., Clark, L., Sin, S., & Gogotsi, Y. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b02847 · Cited by 5,045
Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide
Lukatskaya, M. R., Mashtalir, O., Ren, C. E., Dall’Agnese, Y., Rozier, P., Taberna, P. L., Naguib, M., Simon, P., Barsoum, M. W., & Gogotsi, Y. (2013) · Science · doi:10.1126/science.1241488 · Cited by 4,320
Ran, J., Gao, G., Li, F.-T., Ma, T.-Y., Du, A., & Qiao, S.-Z. (2017) · Nature Communications · doi:10.1038/ncomms13907 · Cited by 2,023
MXene Ti3C2: An Effective 2D Light-to-Heat Conversion Material
Li, R., Zhang, L., Shi, L., & Wang, P. (2017) · ACS Nano · doi:10.1021/acsnano.6b08415 · Cited by 1,798
Cited by
Ten Years of Progress in the Synthesis and Development of MXenes
Naguib, M., Barsoum, M. W., & Gogotsi, Y. (2021) · Advanced Materials · doi:10.1002/adma.202103393 · Cited by 1,257
Recent Advances in Oxidation Stable Chemistry of 2D MXenes
Cao, F., Zhang, Y., Wang, H., Khan, K., Tareen, A. K., Qian, W., Zhang, H., & Ågren, H. (2022) · Advanced Materials · doi:10.1002/adma.202107554 · Cited by 648
MXenes: An Introduction of Their Synthesis, Select Properties, and Applications
Verger, L., Natu, V., Carey, M., & Barsoum, M. W. (2019) · Trends in Chemistry · doi:10.1016/j.trechm.2019.04.006 · Cited by 499
Potential of MXenes in Water Desalination: Current Status and Perspectives
Ihsanullah, I. (2020) · Nano-Micro Letters · doi:10.1007/s40820-020-0411-9 · Cited by 281
Xu, C., Zhang, M., Yin, X., Gao, Q., Jiang, S., Cheng, J., Kong, X., Liu, B., & Peng, H.-Q. (2023) · Journal of Materials Chemistry A · doi:10.1039/d3ta02293e · Cited by 65
Metadata
- Authors
- Yang, S., Zhang, P., Wang, F., Ricciardulli, A. G., Lohe, M. R., Blom, P. W. M., & Feng, X.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-10-24
- Volume
- 57
- Issue
- 47
- Pages
- 15491-15495
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2894781968
- Cited by
- 788
- References
- 28
- FWCI
- 15.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, S., Zhang, P., Wang, F., Ricciardulli, A. G., Lohe, M. R., Blom, P. W. M., & Feng, X. (2018). Fluoride‐Free Synthesis of Two‐Dimensional Titanium Carbide (MXene) Using A Binary Aqueous System. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201809662
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