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Cited by 298

The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.

Palladium Phosphide as a Stable and Efficient Electrocatalyst for Overall Water Splitting

Luo, Fang, Zhang, Quan, Yu, Xinxin, Xiao, Shenglin, Ling, Ying, Hu, Hao, Guo, Long, Yang, Zehui, Huang, Liang, Cai, Weiwei, Cheng, Hansong·2018·Angewandte Chemie International Edition

Abstract

A palladium phosphide electrocatalyst supported on carbon black (PdP 2@CB) shows efficient water splitting in both alkaline and neutral electrolytes. Significantly lower overpotentials are required for PdP 2@CB (27.5 mV in 0.5 m H 2 SO 4; 35.4 mV in 1 m KOH; 84.6 mV in 1 m PBS) to achieve a HER electrocatalytic current density of 10 mA cm−2 compared to commercial Pt/CB (30.1 mV in 0.5 m H 2 SO 4; 46.6 mV in 1 m KOH; 122.7 mV in 1 m PBS). Moreover, no loss in HER activity is detectable after 5000 potential sweeps. Only 270 mV and 277 mV overpotentials are required to reach a current density of 10 mA cm−2 for PdP 2@CB to catalyze OER in 1 m KOH and 1 m PBS electrolytes, which is better OER activity than the benchmark IrO 2 electrocatalyst (301 mV and 313 mV to drive a current density of 10 mA cm−2). 1.59 V and 1.72 V are needed for PdP 2@CB to achieve stable water splitting catalytic current density of 10 mA cm−2 in 1 m PBS and 50 mA cm−2 in 1 m KOH for 10 h, respectively.

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Research works printed but not linked: 4

  1. 10.1039/C7TA01318C · doi:10.1039/c7ta01318c
  2. 10.1039/c3dt50686j · doi:10.1039/c3dt50686j
  3. 10.1021/jp311924q · doi:10.1021/jp311924q
  4. 10.1021/cm0103895 · doi:10.1021/cm0103895

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Metadata

Authors
Luo, F., Zhang, Q., Yu, X., Xiao, S., Ling, Y., Hu, H., Guo, L., Yang, Z., Huang, L., Cai, W., & Cheng, H.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2018-10-12
Volume
57
Issue
45
Pages
14862-14867
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2890177487
Cited by
298
References
47
FWCI
7.58
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Palladium Phosphide as a Stable and Efficient Electrocatalyst for Overall Water Splitting. https://app.cochat.ai/papers/10.1002/anie.201810102
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Luo, F., Zhang, Q., Yu, X., Xiao, S., Ling, Y., Hu, H., Guo, L., Yang, Z., Huang, L., Cai, W., & Cheng, H. (2018). Palladium Phosphide as a Stable and Efficient Electrocatalyst for Overall Water Splitting. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201810102

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