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Heterostructures Composed of N‐Doped Carbon Nanotubes Encapsulating Cobalt and β‐Mo2C Nanoparticles as Bifunctional Electrodes for Water Splitting

Ouyang, Ting, Ye, Ya‐Qian, Wu, Chun‐Yan, Xiao, Kang, Liu, Zhao‐Qing·2019·Angewandte Chemie International Edition

Abstract

Herein, we demonstrate the use of heterostructures comprised of Co/β‐Mo 2 C@N‐CNT hybrids for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in an alkaline electrolyte. The Co can not only create a well‐defined heterointerface with β‐Mo 2 C but also overcomes the poor OER activity of β‐Mo 2 C, thus leading to enhanced electrocatalytic activity for HER and OER. DFT calculations further proved that cooperation between the N‐CNTs, Co, and β‐Mo 2 C results in lower energy barriers of intermediates and thus greatly enhances the HER and OER performance. This study not only provides a simple strategy for the construction of heterostructures with nonprecious metals, but also provides in‐depth insight into the HER and OER mechanism in alkaline solution.

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Metadata

Authors
Ouyang, T., Ye, Y., Wu, C., Xiao, K., & Liu, Z.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2019-02-04
Volume
58
Issue
15
Pages
4923-4928
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2909790116
Cited by
804
References
56
FWCI
27.93
Type
journal article
Language
en
Open access
closed
Funders
  • National Natural Science Foundation of China (21875048, 21576056, and 21576057)
  • Natural Science Foundation of Shanghai (2017A030311016, 2018A030310339)

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CoChat. (2026). Citation check: Heterostructures Composed of N‐Doped Carbon Nanotubes Encapsulating Cobalt and β‐Mo2C Nanoparticles as Bifunctional Electrodes for Water Splitting. https://app.cochat.ai/papers/10.1002/anie.201814262
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Ouyang, T., Ye, Y., Wu, C., Xiao, K., & Liu, Z. (2019). Heterostructures Composed of N‐Doped Carbon Nanotubes Encapsulating Cobalt and β‐Mo2C Nanoparticles as Bifunctional Electrodes for Water Splitting. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201814262

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