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Incorporation of Homochirality into a Zeolitic Imidazolate Framework Membrane for Efficient Chiral Separation
Open accessAbstract
Homochiral metal–organic frameworks (MOFs) have gained much attention because of their chiral properties and disposition for chiral separation. However, the fabrication of high‐quality homochiral MOF membranes remains challenging because of the difficulty in controlling growth of MOF membranes with chiral functionalities. A homochiral zeolitic imidazolate framework‐8 (ZIF‐8) membrane is reported for efficient chiral separation. The membrane is synthesized by incorporating a natural amino acid, l‐histidine (l‐His), into the framework of ZIF‐8. The homochiral l‐His‐ZIF‐8 membrane exhibits a good selectivity for the R‐enantiomer of 1‐phenylethanol over the S‐enantiomer, showing a high enantiomeric excess value up to 76 %.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Chirality in adsorption on solid surfaces
Zaera, F. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00367f · Cited by 172
Cited by
Chiral Metal–Organic Frameworks
Gong, W., Chen, Z., Dong, J., Liu, Y., & Cui, Y. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00740 · Cited by 579
Advances in metal–organic framework-based membranes
Cheng, Y., Datta, S. J., Zhou, S., Jia, J., Shekhah, O., & Eddaoudi, M. (2022) · Chemical Society Reviews · doi:10.1039/d2cs00031h · Cited by 423
Microporous framework membranes for precise molecule/ion separations
Dou, H., Xu, M., Wang, B., Zhang, Z., Wen, G., Zheng, Y., Luo, D., Zhao, L., Yu, A., Zhang, L., et al. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00552e · Cited by 371
Peluso, P., & Chankvetadze, B. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00846 · Cited by 371
Metadata
- Authors
- Chan, J. Y., Zhang, H., Nolvachai, Y., Hu, Y., Zhu, H., Forsyth, M., Gu, Q., Hoke, D. E., Zhang, X., Marriot, P. J., & Wang, H.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-11-27
- Volume
- 57
- Issue
- 52
- Pages
- 17130-17134
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2899355930
- Cited by
- 181
- References
- 2
- FWCI
- 5.12
- Type
- journal article
- Language
- en
- Open access
- green
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- Chan, J. Y., Zhang, H., Nolvachai, Y., Hu, Y., Zhu, H., Forsyth, M., Gu, Q., Hoke, D. E., Zhang, X., Marriot, P. J., & Wang, H. (2018). Incorporation of Homochirality into a Zeolitic Imidazolate Framework Membrane for Efficient Chiral Separation. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201810925
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