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Conductance Photoswitching of Metal–Organic Frameworks with Embedded Spiropyran
Open accessAbstract
Conductive metal–organic frameworks (MOFs) as well as smart, stimuli‐responsive MOF materials have attracted considerable attention with respect to advanced applications in energy harvesting and storage as well as in signal processing. Here, the conductance of MOF films of type UiO‐67 with embedded photoswitchable nitro‐substituted spiropyrans was investigated. Under UV irradiation, the spiropyran (SP) reversibly isomerizes to the open merocyanine (MC) form, a zwitterionic molecule with an extended conjugated π‐system. The light‐induced SP–MC isomerization allows for remote control over the conductance of the SP@UiO‐67 MOF film, and the conductance can be increased by one order of magnitude. This research has the potential to contribute to the development of a new generation of photoelectronic devices based on smart hybrid materials.
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Electron transfer reactions in chemistry. Theory and experiment
Marcus, R. A. (1993) · Reviews of Modern Physics · doi:10.1103/revmodphys.65.599 · Cited by 3,667
Cited by
Molecular photoswitches in aqueous environments
Volarić, J., Szymanski, W., Simeth, N. A., & Feringa, B. L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00547a · Cited by 438
Photophysics Modulation in Photoswitchable Metal–Organic Frameworks
Rice, A. M., Martin, C. R., Galitskiy, V. A., Berseneva, A. A., Leith, G. A., & Shustova, N. B. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00350 · Cited by 432
Heinke, L., & Wöll, C. (2019) · Advanced Materials · doi:10.1002/adma.201806324 · Cited by 192
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Metadata
- Authors
- Garg, S., Schwartz, H., Kozlowska, M., Kanj, A. B., Müller, K., Wenzel, W., Ruschewitz, U., & Heinke, L.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-12-20
- Volume
- 58
- Issue
- 4
- Pages
- 1193-1197
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2905623109
- Cited by
- 158
- References
- 1
- FWCI
- 5.55
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Garg, S., Schwartz, H., Kozlowska, M., Kanj, A. B., Müller, K., Wenzel, W., Ruschewitz, U., & Heinke, L. (2019). Conductance Photoswitching of Metal–Organic Frameworks with Embedded Spiropyran. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201811458
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