The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Boosting Electrochemical CO2 Reduction on Metal–Organic Frameworks via Ligand Doping
Abstract
Electrochemical CO 2 reduction relies on the availability of highly efficient and selective catalysts. Herein, we report a general strategy to boost the activity of metal–organic frameworks (MOFs) towards CO 2 reduction via ligand doping. A strong electron‐donating molecule of 1,10‐phenanthroline was doped into Zn‐based MOFs of zeolitic imidazolate framework‐8 (ZIF‐8) as CO 2 reduction electrocatalyst. Experimental and theoretical evidences reveal that the electron‐donating nature of phenanthroline enables a charge transfer, which induces adjacent active sites at the sp 2 C atoms in the imidazole ligand possessing more electrons, and facilitates the generation of *COOH, hence leading to improved activity and Faradaic efficiency towards CO production.
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Cites
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Zhong, H., Wang, J., Zhang, Y., Xu, W., Xing, W., Xu, D., Zhang, Y., & Zhang, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201408990 · Cited by 938
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Cited by
Defect Chemistry in Heterogeneous Catalysis: Recognition, Understanding, and Utilization
Xie, C., Yan, D., Li, H., Du, S., Chen, W., Wang, Y., Zou, Y., Chen, R., & Wang, S. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c03034 · Cited by 623
Electrocatalytic reduction of carbon dioxide: opportunities with heterogeneous molecular catalysts
Sun, L., Reddu, V., Fisher, A. C., & Wang, X. (2020) · Energy & Environmental Science · doi:10.1039/c9ee03660a · Cited by 452
Self-citationYounas, M., Rezakazemi, M., Daud, M., Wazir, M. B., Ahmad, S., Ullah, N., Inamuddin, & Ramakrishna, S. (2020) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2020.100849 · Cited by 421
Li, J., Shen, H., Ma, C., Zhang, H., Luo, P., Chen, J., Mu, M., & Yin, X. (2023) · Electrochimica Acta · doi:10.1016/j.electacta.2023.141896 · Cited by 23
Metadata
- Authors
- Dou, S., Song, J., Xi, S., Du, Y., Wang, J., Huang, Z., Xu, Z. J., & Wang, X.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-02-14
- Volume
- 58
- Issue
- 12
- Pages
- 4041-4045
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2913130213
- Cited by
- 301
- References
- 2
- FWCI
- 7.27
- Type
- journal article
- Language
- en
- Open access
- closed
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- Dou, S., Song, J., Xi, S., Du, Y., Wang, J., Huang, Z., Xu, Z. J., & Wang, X. (2019). Boosting Electrochemical CO2 Reduction on Metal–Organic Frameworks via Ligand Doping. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201814711
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